nanostructured materials;
optical materials;
rare-earth alloys and compounds;
chemical synthesis;
nanofabrication;
NANOCRYSTALS;
CERAMICS;
D O I:
10.1016/j.jallcom.2007.04.111
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
PbF2:Yb-Er nanoparticles were synthesized by two different ways: a pseudo-micellar route and the selective dissolution of the oxide glassy matrix of an oxyfluoride composite glass-ceramic obtained by Yb-Er induced nucleation of PbF2 inside the GeO2:PbO:PbF2 glass. Both nanoparticles exhibit strong visible up-conversion fluorescence after infrared excitation. S-4(3/2) level lifetime of Er3+ ions reflects the high specific surface of the particles and their ability to adsorb quenching centres. (c) 2007 Elsevier B.V. All rights reserved.