Phenomenological Approach to the Critical Slowing Down in Pyridinium Tetrafluoroborate Single Crystals

被引:1
作者
Iwata, Makoto [1 ]
Ninoseki, Kenta [1 ]
Odani, Shunsuke [1 ]
Takikawa, Yoshinori [1 ]
机构
[1] Nagoya Inst Technol, Grad Sch Engn, Dept Phys Sci & Engn, Nagoya, Aichi 4668555, Japan
关键词
PHASE-TRANSITION; FERROELECTRIC PROPERTIES; DIELECTRIC-RELAXATION; LANDAU THEORY; HIGH-PRESSURE; DISPERSION; DYNAMICS;
D O I
10.7566/JPSJ.87.124708
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The dielectric dispersion in pyridinium tetrafluoroborate single crystals has been measured in the frequency range from 300 Hz to 10 MHz. In the vicinity of the paraelectrio-to-ferroelectric phase transition temperature T-cl, dielectric critical slowing down has been observed, where one Debye-type relaxation mode in the paraelectric phase splits into two Debye-type relaxation modes below T-cl. Our experimental data for the phase transition at T-cl were analyzed on the basis of the Landau-type phenomenology.
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页数:6
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共 35 条
[1]   2H NMR study of dynamics, ordering, and phase transitions in ferroelectric pyridinium tetrafluoroborate [J].
Beck, B ;
Villanueva-Garibay, JA ;
Müller, K ;
Roduner, E .
CHEMISTRY OF MATERIALS, 2003, 15 (08) :1739-1748
[2]   Reorientational dynamics of aza-cyclohexadienyl radicals in pyridinium tetrafluoroborate [J].
Beck, B ;
Roduner, E ;
Dilger, H ;
Czarnecki, P ;
Fleming, DG ;
Reid, ID ;
Rhodes, CJ .
PHYSICA B, 2000, 289 :607-611
[3]   LATTICE MODES IN FERROELECTRIC PEROVSKITES - PBTIO3 [J].
BURNS, G ;
SCOTT, BA .
PHYSICAL REVIEW B, 1973, 7 (07) :3088-3101
[4]   CRYSTAL STRUCTURES OF PYRIDINIUM SALTS OF GROUP VB HEXAFLUORIDE ANIONS [J].
COPELAND, RF ;
CONNER, SH ;
MEYERS, EA .
JOURNAL OF PHYSICAL CHEMISTRY, 1966, 70 (04) :1288-&
[6]   FERROELECTRIC PROPERTIES OF PYRIDINIUM TETRAFLUOROBORATE [J].
CZARNECKI, P ;
NAWROCIK, W ;
PAJAK, Z ;
WASICKI, J .
PHYSICAL REVIEW B, 1994, 49 (02) :1511-1512
[7]  
Czarnecki P, 1998, PHYS STATUS SOLIDI B, V209, P211, DOI 10.1002/(SICI)1521-3951(199809)209:1<211::AID-PSSB211>3.0.CO
[8]  
2-F
[9]   Experimental evidence for a continuous phase transition in a multidimensional ferroelectric [J].
Czarnecki, P ;
Katrusiak, A ;
Szafraniak, I ;
Wasicki, J .
PHYSICAL REVIEW B, 1998, 57 (06) :3326-3332
[10]   Structural phase transitions of pyridinium tetrafluoroborate [J].
Czarnecki, P ;
Wasicki, J ;
Katrusiak, A ;
Ecolivet, C ;
Girard, A ;
Belushkin, A .
PHYSICA B, 1997, 234 :102-103