Thermodynamic properties of metal-carbon melts

被引：4
作者：
Kudin, VG [1 ]
Makara, VA [1 ]
机构：
[1] Shevchenko Natl Univ, UA-01033 Kiev, Ukraine
来源：
INORGANIC MATERIALS | 2005年 / 41卷 / 06期
关键词：
Experimental Data; Carbide; Enthalpy; Inorganic Chemistry; Calorimetry;
D O I：
10.1007/s10789-005-0175-0
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
The partial and total enthalpies of mixing of Si-C and Ni-C liquid alloys at 2000 K are determined by isoperibol calorimetry. The mixing enthalpies in these systems are found to be small and negative, in agreement with earlier results. The thennochemical properties of dilute Al-C solutions are studied at 1773 K for the first time. The mixing enthalpies of metal-carbon melts are estimated from the standard enthalpies of formation of metal carbides. The calculated mixing enthalpies of liquid metal-carbon alloys agree with experimental data.
引用
收藏
页码：591 / 594
页数：4
相关论文
共 50 条
  • [31] Thermodynamic properties of multiwalled carbon nanotubes
    V. B. Muratov
    O. O. Vasil’ev
    L. M. Kulikov
    V. V. Garbuz
    Yu. V. Nesterenko
    T. I. Duda
    Journal of Superhard Materials, 2012, 34 : 173 - 178
  • [32] The thermodynamic properties of rare-earth metal binuclear acetates and pivalates
    Zh. V. Dobrokhotova
    I. G. Fomina
    M. A. Kiskin
    M. A. Bykov
    G. V. Belov
    V. M. Novotortsev
    Russian Journal of Physical Chemistry, 2006, 80 : 323 - 329
  • [33] Thermodynamic properties of melts in Al-TI(Zr, Hf) binary systems
    Sudavtsova, V. S.
    Podoprigora, N. V.
    POWDER METALLURGY AND METAL CERAMICS, 2009, 48 (1-2) : 83 - 87
  • [34] Solubility and thermodynamic properties of alkali metal unanoborates
    N. G. Chernorukov
    O. V. Nipruk
    A. V. Knyazev
    V. O. Khomyakova
    Radiochemistry, 2003, 45 (3) : 273 - 275
  • [35] Thermodynamic properties of Mn-Y-Si(Ge, Sn, Pb, C) melts
    V. S. Sudavtsova
    N. V. Kotova
    Inorganic Materials, 2008, 44 : 1091 - 1096
  • [36] Mixing enthalpies in samarium–transition metal melts
    V. V. Berezutskii
    M. I. Ivanov
    Powder Metallurgy and Metal Ceramics, 2009, 48 : 454 - 461
  • [37] Thermodynamic properties of Ga-In-Li alloys - a potential material for liquid metal batteries
    Zabrocki, M.
    Gasior, W.
    Debski, A.
    JOURNAL OF MOLECULAR LIQUIDS, 2021, 332
  • [38] Thermodynamic Properties of β-Sialon
    A. V. Zabolotskii
    N. V. Dolgushev
    S. A. Suvorov
    Inorganic Materials, 2002, 38 : 224 - 226
  • [39] Mixing enthalpies in samarium-transition metal melts
    Berezutskii, V. V.
    Ivanov, M. I.
    POWDER METALLURGY AND METAL CERAMICS, 2009, 48 (7-8) : 454 - 461
  • [40] Thermodynamic properties of β-sialon
    Zabolotskii, AV
    Dolgushev, NV
    Suvorov, SA
    INORGANIC MATERIALS, 2002, 38 (03) : 224 - 226
12345