Solution Combustion Synthesis: Towards a Sustainable Approach for Metal Oxides

被引:176
作者
Carlos, Emanuel [1 ,2 ]
Martins, Rodrigo [1 ,2 ]
Fortunato, Elvira [1 ,2 ]
Branquinho, Rita [1 ,2 ]
机构
[1] UNL, FCT, CENIMAT, Dept Mat Sci,i3N, P-2829516 Caparica, Portugal
[2] Univ Nova Lisboa, CEMOP, P-2829516 Caparica, Portugal
基金
欧洲研究理事会; 欧盟地平线“2020”;
关键词
fuel; metal oxides; nanostructures; solution combustion synthesis; thin film transistors; THIN-FILM TRANSISTORS; HIGH-SURFACE-AREA; SINGLE-STEP SYNTHESIS; SNO2 QUANTUM DOTS; SOL-GEL; LOW-TEMPERATURE; ZNO NANOPARTICLES; MAGNETIC-PROPERTIES; PHOTOCATALYTIC ACTIVITY; THERMAL-DECOMPOSITION;
D O I
10.1002/chem.202000678
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Solution combustion synthesis (SCS) has been widely used to produce simple and complex oxides with a desired morphology (size and shape). SCS is valuable due to low cost, simplicity and energy efficient synthesis. To guarantee the best molecular-level mixing of reactants in an aqueous or solvent-based solution some parameters need to be controlled, such as fuel type, metal cations precursors, stoichiometry ratio (phi), pH effect, atmosphere and initiation type. These determine the final properties of the oxide materials, providing the potential to reach different morphologies, which are essential for their final applications. This Review article focuses on the crucial parameters in SCS and how these affect the overall materials properties from nanostructures to thin films. To finalize, special attention is given to the application of SCS to form metal oxide thin films at low temperature and their application in thin film transistors (TFTs).
引用
收藏
页码:9099 / 9125
页数:27
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