Effect of Al3+ substitution on the structural, magnetic, and electric properties in multiferroic Bi2Fe4O9 ceramics

Structural, magnetic, and electric properties have been investigated in polycrystalline Bi-2(Fe1-xAlx)(4)O-9 (0 <= x <= 0.25) ceramics synthesized by a modified Pechini method. Structural analysis reveals that Al3+ doped Bi2Fe4O9 crystallizes in orthorhombic structure with Pbnm space group. Surface morphology of the end products is examined by scanning electron microscopy and the grain size has a tendency to decrease with increase in Al3+ doping level. Compared with pure Bi2Fe4O9, room temperature coexistent multiferroic-like behavior is observed in Al3+ doped Bi2Fe4O9. By analyzing magnetic properties, the Neel temperature monotonously shifts to low temperatures from similar to 260 K (x=0) to 35 K (x=0.25). Moreover, the spin dynamic measured by the shift in ac magnetic susceptibility as a function of frequency provides a possibility of spin-glass-like behavior, which is further confirmed by fitting the critical slowing down power law and memory effect. (C) 2015 Elsevier Inc. All rights reserved.