Synthesis and characterization of hydroxycarboxylato complexes of nickel(II)

被引：0
|
作者：
Baranwal, BP [1 ]
Das, SS [1 ]
Singh, P [1 ]
Gupta, T [1 ]
机构：
[1] D D U Gorakhpur Univ, Dept Chem, Gorakhpur 273009, Uttar Pradesh, India
来源：
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2001年 / 40卷 / 03期
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D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Acetate groups of anhydrous nickel(II) acetate have been substituted with some higher carboxylic acids and hydroxycarboxylic acids in toluene under reflux and the products Ni(OOCR)(OOCR'), Ni(OOCR)(OOCR ") and Ni(OOCR)(OOCR''') [where R=C13H27, C17H35 or C21H43 and R'=C6H4OH, R " =C6H5CH(OH) and R'''=(C6H5)(2)C(OH)] obtained have been characterized by elemental analyses, electronic and IR spectra and conductivity measurements. An octahedral environment around nickel(II) ion is suggested and the molecular weight determinations confirm the dinuclear nature of these complexes.
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页码：320 / 322
页数：3
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