Cycloadditions of Allylsilanes - Part 22. Stereoselective Synthesis of Cyclopentanes and Cyclobutanes by Lewis Acid Promoted [3+2] and [2+2] Cycloadditions of Allylsilanes

被引：35

作者：

Schmidt, Arndt W. ^{[1
]}

Knoelker, Hans-Joachim ^{[1
]}

机构：

[1] Tech Univ Dresden, Dept Chem, D-01069 Dresden, Germany

来源：

SYNLETT | 2010年 / 15期

关键词：

annulations; cycloadditions; enones; Lewis acids; silicon; STEREOCONTROLLED TOTAL-SYNTHESIS; OPTICALLY-ACTIVE ALLYLSILANES; OCCURRING TERPENE DERIVATIVES; HYDROGEN-PEROXIDE OXIDATION; TRANSITION-METAL-COMPLEXES; SCALE ASPIDIOTUS-NERII; ORGANIC-SYNTHESIS; ASYMMETRIC-SYNTHESIS; CONJUGATE ADDITION; ABSOLUTE-CONFIGURATION;

D O I：

10.1055/s-0030-1258549

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The development of Lewis acid promoted [3+2] and [2+2] cycloadditions as a novel methodology for the stereoselective construction of cyclopentanes and cyclobutanes is described. Elegant applications of this methodology to the total synthesis of biologically active terpenoid natural products are presented.

引用

页码：2207 / 2239

页数：33

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