Photophysical, electrochemical, thermal and aggregation properties of new metal phthalocyanines

被引:35
作者
Jeong, Jaemyeng [1 ]
Kumar, Rangaraju Satish [1 ]
Mergu, Naveen [1 ]
Son, Young-A. [1 ]
机构
[1] Chungnam Natl Univ, Dept Adv Organ Mat Engn, 220 Gung Dong, Daejeon 305764, South Korea
关键词
Phthalocyanine; Peripheral; Density functional theory; Binding; Aggregation; FLUORESCENCE PROPERTIES; ZINC PHTHALOCYANINES; THIN-FILMS; METALLOPHTHALOCYANINES; STABILITY; COMPLEXES; TETRA;
D O I
10.1016/j.molstruc.2017.06.125
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study, the synthesis of di(ethylene glycol) naphthalene substituted metal-phthalocyanines was reported. These novel phthalocyanines were characterized by elemental and spectroscopic analysis, including H-1 NMR, FT-IR, UV-Vis spectral and MALDI-TOF mass data. The aggregation behavior of these phthalocyanines was examined in chloroform at different concentrations, and we confirmed that the phthalocyanines were non-aggregated. Further thermal stability, electrochemical, theoretical studies and metal sensing properties also investigated. In addition, we successfully prepared phthalocyanine (6d) blended polyurethane electrospun (ES) nanofibers. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:469 / 479
页数:11
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