Photophysical, electrochemical, thermal and aggregation properties of new metal phthalocyanines

被引：35

作者：

Jeong, Jaemyeng ^{[1
]}

Kumar, Rangaraju Satish ^{[1
]}

Mergu, Naveen ^{[1
]}

Son, Young-A. ^{[1
]}

机构：

[1] Chungnam Natl Univ, Dept Adv Organ Mat Engn, 220 Gung Dong, Daejeon 305764, South Korea

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2017年 / 1147卷

关键词：

Phthalocyanine; Peripheral; Density functional theory; Binding; Aggregation; FLUORESCENCE PROPERTIES; ZINC PHTHALOCYANINES; THIN-FILMS; METALLOPHTHALOCYANINES; STABILITY; COMPLEXES; TETRA;

D O I：

10.1016/j.molstruc.2017.06.125

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In this study, the synthesis of di(ethylene glycol) naphthalene substituted metal-phthalocyanines was reported. These novel phthalocyanines were characterized by elemental and spectroscopic analysis, including H-1 NMR, FT-IR, UV-Vis spectral and MALDI-TOF mass data. The aggregation behavior of these phthalocyanines was examined in chloroform at different concentrations, and we confirmed that the phthalocyanines were non-aggregated. Further thermal stability, electrochemical, theoretical studies and metal sensing properties also investigated. In addition, we successfully prepared phthalocyanine (6d) blended polyurethane electrospun (ES) nanofibers. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：469 / 479

页数：11

共 63 条

[1] Metal complexes as photo- and radiosensitizers [J].

Ali, H ;

van Lier, JE .

CHEMICAL REVIEWS, 1999, 99 (09) :2379-2450

[2] Peripheral octa-substituted metal-free, cobalt(II) and zinc(II) phthalocyanines bearing coumarin and chloro groups: Synthesis, characterization, spectral and electrochemical properties [J].

Altun, Selcuk ;

Ozkaya, Ali Riza ;

Bulut, Mustafa .

POLYHEDRON, 2012, 48 (01) :31-42

[3]

[Anonymous], 2012, PHOTOSENSITIZERMED

[4]

[Anonymous], ADV ORGANIC CHEM REA

[5]

[Anonymous], PORPHYRIN HDB PHTHAL

[6]

[Anonymous], P INT C

[7] Thin films of fluorinated 3d-metal phthalocyanines as chemical sensors of ammonia: An optical spectroscopy study [J].

Basova, Tamara V. ;

Mikhaleva, Natalia S. ;

Hassan, Aseel K. ;

Kiselev, Vitaly G. .

SENSORS AND ACTUATORS B-CHEMICAL, 2016, 227 :634-642

[8] Composites of liquid crystalline nickel phthalocyanine with gold nanoparticles: Liquid crystalline behaviour and optical properties [J].

Basova, Tamara V. ;

Parkhomenko, Roman G. ;

Igumenov, Igor K. ;

Hassan, Aseel ;

Durmus, Mahmut ;

Gurek, Ayse Gul ;

Ahsen, Vefa .

DYES AND PIGMENTS, 2014, 111 :58-63

[9] Novel non-aggregated soluble metallophthalocyanines bearing carboxylic acid groups [J].

Bayar, Serife ;

Dincer, Hatice A. ;

Ugur, Ahmet L. .

JOURNAL OF COORDINATION CHEMISTRY, 2012, 65 (08) :1371-1380

[10] Synthesis and photophysicochemical properties of novel water soluble phthalocyanines [J].

Cakir, Volkan ;

Goksel, Meltem ;

Durmus, Mahmut ;

Biyiklioglu, Zekeriya .

DYES AND PIGMENTS, 2016, 125 :414-425

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