Mesomorphic di- and tetra-fluorinated imines and their complexes with Re1

被引：19

作者：

Liu, XH

Manners, I ^{[1
]}

Bruce, DW

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

[2] Univ Exeter, Dept Chem, Exeter EX4 4QD, Devon, England

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1998年 / 8卷 / 07期

关键词：

D O I：

10.1039/a802167h

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The synthesis of some di- and tetra-fluoro imine mesogens is described and their mesomorphism is compared with that of the parent, unfluorinated materials. The comparison reveals that in the fluorinated compounds, more ordered smectic phases were suppressed and crystal phases were destabilised; nematic phases were uniformly destabilised. The imines were then reacted with [ReMe(CO)(5)] to give related orthometallated complexes which were also mesomorphic.

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页码：1555 / 1560

页数：6

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