High H2 adsorption in a microporous metal-organic framework with open metal sites

被引：1048
作者：
Chen, BL [1 ]
Ockwig, NW
Millward, AR
Contreras, DS
Yaghi, OM
机构：
[1] Univ Texas Pan Amer, Dept Chem, Edinburgh 78541, Midlothian, Scotland
[2] Univ Michigan, Dept Chem, Mat Design & Discovery Grp, Ann Arbor, MI 48109 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 30期
关键词：
adsorption; copper; hydrogen; metal-organic frameworks; microporous materials;
D O I：
10.1002/anie.200462787
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A copper-based metal-organic framework (MOF) has been synthesized, and its structure has been solved by X-ray crystallography (see picture; Cu blue, C black, O red, framework pore yellow). The remarkably high hydrogen adsorption properties (2.47 wt%) of this compound have been studied. (Chemical Equation Presented) © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：4745 / 4749
页数：5
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