Bis[μ-1-(2-pyridyl-κN)ethanone 4-phenylthiosemicarbazonato-κ2 N1,S]bis[iodomercury(II)]

被引：0
|
作者：
Yamin, BM [1 ]
Yusof, MSM [1 ]
机构：
[1] Univ Kebangsaan Malaysia, Sch Chem Sci & Food Technol, Bangi 43600, Selangor, Malaysia
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷
关键词：
D O I：
10.1107/S1600536805002898
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Hg-2(C14H13N4S)(2)I-2], is a dimeric complex of mercury(II) with the N,N,S-tridentate electron-donor Schiff base ligand and lies on a crystallographic twofold axis. The two Hg atoms are linked by two bridging S atoms, forming a rectangular base with Hg-S bond lengths of 2.6490 (12) and 2.6173 (11) Angstrom. The two tridentate ligands are almost perpendicular to the base, resulting in an open box-like structure. The geometry of the Hg atoms is between trigonal bipyramidal and square pyramidal, but closer to the latter.
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页码：M454 / M456
页数：3
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