The facile synthesis and characterization of tetraimido-substituted zinc phthalocyanines

被引:10
作者
Cong, Fangdi [1 ]
Ning, Bo [2 ]
Ji, Yiping [3 ]
Wang, Xiuyan [1 ]
Ke, Fubo [1 ]
Liu, Yunyu [1 ]
Cui, Xiujun [1 ]
Chen, Bin [1 ]
机构
[1] NE Normal Univ, Fac Chem, Changchun 130024, Peoples R China
[2] Changchun Vocat Inst Technol, Sch Engn, Changchun 130033, Peoples R China
[3] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China
关键词
phthalocyanine; synthesis; acidylation; characterization; property; UV-vis;
D O I
10.1016/j.dyepig.2007.07.010
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Peripherally tetraimido-substituted zinc phthalocyanines were synthesized by the reaction of tetraamino-substituted zinc phthalocyanine with maleic anhydride, phthalic anhydride and tetrachlorophthalic acid, respectively. The compounds were characterized by MS, (1)H NMR, UV-vis, IR and elemental analysis, the results of which were consistent with the proposed structures. UV-vis spectra showed that the wavelengths of the Q bands followed the order: Q(2c) > Q(2b) > Q(2a); the strengths of the Q bands varied inversely with temperature. The compounds were stable in acid but unstable in alkali. (c) 2007 Published by Elsevier Ltd.
引用
收藏
页码:686 / 690
页数:5
相关论文
共 25 条
[1]   Spectral study of the supramolecular assemblies porphyrins-phthalocyanines [J].
Agirtas, S ;
Ion, RM ;
Bekaroglu, O .
MATERIALS SCIENCE & ENGINEERING C-BIOMIMETIC AND SUPRAMOLECULAR SYSTEMS, 2000, 7 (02) :105-110
[2]   Synthesis and characterization of liquid crystalline tetra- and octa-substituted novel phthalocyanines [J].
Atilla, Devrim ;
Aslibay, Goekhan ;
Guerek, Ayse G. ;
Can, Hatice ;
Ahsen, Vefa .
POLYHEDRON, 2007, 26 (05) :1061-1069
[3]   Synthesis and characterization of novel soluble octa-cationic phthalocyanines [J].
Bayir, ZA .
DYES AND PIGMENTS, 2005, 65 (03) :235-242
[4]   Structural characterisation of a red phthalocyanine [J].
Burnham, PM ;
Cook, MJ ;
Gerrard, LA ;
Heeney, MJ ;
Hughes, DL .
CHEMICAL COMMUNICATIONS, 2003, (16) :2064-2065
[5]   NEW SEMICONDUCTOR-DEVICE PHYSICS IN POLYMER DIODES AND TRANSISTORS [J].
BURROUGHES, JH ;
JONES, CA ;
FRIEND, RH .
NATURE, 1988, 335 (6186) :137-141
[6]   The control of phthalocyanine properties through nitro-group electronic effect [J].
Cong, FD ;
Ning, B ;
Yu, HF ;
Cui, XJ ;
Chen, B ;
Cao, SG ;
Ma, CY .
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2005, 62 (1-3) :394-397
[7]   Facile synthesis, characterization and property comparisons of tetraaminometallophthylocyanines with and without intramolecular hydrogen bonds [J].
Cong, FD ;
Ning, B ;
Du, XG ;
Ma, CY ;
Yu, HF ;
Chen, B .
DYES AND PIGMENTS, 2005, 66 (02) :149-154
[8]   Tuning of phthalocyanine absorption ranges by additional substituents [J].
Dincer, Hatice A. ;
Gul, Ahmet ;
Kocak, Makbule B. .
DYES AND PIGMENTS, 2007, 74 (03) :545-550
[9]   Photosensitizing properties of a boronated phthalocyanine: studies at the molecular and cellular level [J].
Fabris, C ;
Jori, G ;
Giuntini, F ;
Roncucci, G .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY, 2001, 64 (01) :1-7
[10]  
FAN MG, 2001, FUNDAMENTAL PRINCIPL, P2