The D2h distortion around the Cu2+ center in Cu0.5Zr2(PO4)3 single crystals

被引：0
作者：
Huang, Y [1 ]
Du, ML [1 ]
Ni, C [1 ]
Wen, JE [1 ]
机构：
[1] SW Univ Nationalities, Dept Phys, Chengdu 610041, Peoples R China
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES | 2005年 / 60卷 / 03期
关键词：
Cu0.5Zr2(PO4)(3) crystal; gyromagnetic factor; D-2h distortion;
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A formula for the calculation of the three g factors of 3d(9) ions in an orthorhombic field D-2h has been derived. Using it to investigate the EPR g factors of the Cu2+ ions in single crystals of Cu0.5Zr2(PO4)(3), the variation of the g factors on changing the angle a between the x- and y-axis has been explained. According to that, it can be confirmed that the angle a of the D2h distortion is about 62.6 degrees.
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收藏
页码：193 / 195
页数：3
相关论文
共 15 条
  • [1] ELECTRON-SPIN-RESONANCE STUDIES ON SOME COPPER(II) COMPLEXES WITH A FEW NITROGEN DONORS DERIVED FROM PYRIDINE
    AHUJA, IS
    TRIPATHI, S
    [J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1991, 47 (05): : 637 - 641
  • [2] BENNOUNA I, 1994, J SOLID STATE CHEM, V112, P224
  • [3] BUSSEREAU I, 1989, EUR J SOL STATE INOR, V26, P383
  • [4] DEBNATH R, 1995, PHYS CHEM GLASSES, V36, P160
  • [5] ElJazouli A, 1994, ADV MAT RES, V1-2, P105, DOI 10.4028/www.scientific.net/AMR.1-2.105
  • [6] THE NASICON-LIKE COPPER(II) ZIRCONIUM-PHOSPHATE CU0.5ZR2(PO4)3 AND RELATED-COMPOUNDS
    ELJAZOULI, A
    ALAMI, M
    BROCHU, R
    DANCE, JM
    LEFLEM, G
    HAGENMULLER, P
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1987, 71 (02) : 444 - 450
  • [7] AN EXAFS INVESTIGATION ON COPPER(I-II) RELATED NASICON-TYPE PHOSPHATES
    FARGIN, E
    BUSSEREAU, I
    OLAZCUAGA, R
    LEFLEM, G
    CARTIER, C
    DEXPERT, H
    [J]. JOURNAL OF SOLID STATE CHEMISTRY, 1994, 112 (01) : 176 - 181
  • [8] CRYSTAL STRUCTURE OF NAME2 4(PO4)3 - ME4 =GE TI ZR
    HAGMAN, LO
    KIERKEGA.P
    [J]. ACTA CHEMICA SCANDINAVICA, 1968, 22 (06): : 1822 - &
  • [9] CU2+ IN AMMONIUM FLUORIDE - TETRAHEDRAL SITE
    PARKER, IH
    [J]. JOURNAL OF PHYSICS PART C SOLID STATE PHYSICS, 1971, 4 (17): : 2967 - &
  • [10] SYNTHESIS, CHARACTERIZATION AND CATALYTIC BEHAVIOR OF CU05M2(PO4)3 (M-EQUIVALENT-TO-ZR, SN, TI)
    SERGHINI, A
    BROCHU, R
    ZIYAD, M
    VEDRINE, JC
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 1992, 188 (1-2) : 60 - 64
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