A nickel-catalyzed route to pyridines

被引：197

作者：

McCormick, MM ^{[1
]}

Duong, HA ^{[1
]}

Zuo, G ^{[1
]}

Louie, J ^{[1
]}

机构：

[1] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 14期

关键词：

D O I：

10.1021/ja0508931

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A mild and general route for preparing pyridines from nitriles and diynes is described. Ni/imidazolyidene complexes were used to mediate cyclization alkynes and both aryl and alkyl nitriles at ambient temperature. In addition, the efficacy of this protocol allows for the preparation of a fused seven-membered pyridone and for intermolecular cyclizations. When an asymmetrical diyne was employed, cyclization afforded a single pyridine regioisomer. Copyright © 2005 American Chemical Society.

引用

收藏

页码：5030 / 5031

页数：2

相关论文

共 50 条

[41] NICKEL-CATALYZED REACTIONS INVOLVING STRAINED BONDS .9. NICKEL-CATALYZED ISOMERIZATION OF METHYLENECYCLOPROPANE TO BUTADIENE [J].

TAKAYA, H ;

HAYASHI, N ;

ISHIGAMI, T ;

NOYORI, R .

CHEMISTRY LETTERS, 1973, (08) :813-816

[42] Nickel-catalyzed rearrangements of vinylcyclopropanes and cyclopropylenynes [J].

Zuo, G ;

Louie, J .

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 :U3258-U3259

[43] Nickel-catalyzed cycloaddition of alkynes and isocyanates [J].

Duong, H ;

Louie, J .

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2005, 230 :U3249-U3250

[44] Nickel-Catalyzed Asymmetric Hydrocyanation of Allenes [J].

Long, Jinguo ;

Gao, Jihui ;

Fang, Xianjie .

ORGANIC LETTERS, 2020, 22 (02) :376-380

[45] Nickel-catalyzed Reactions of Enone with Ethylene [J].

Nishimura, A. ;

Haba, T. ;

Ohashi, M. ;

Ogoshi, S. .

FOURTH INTERNATIONAL SYMPOSIUM ON ATOMIC TECHNOLOGY, 2010, 232

[46] Nickel-catalyzed silaborative dimerization of alkynes [J].

Suginome, M ;

Matsuda, T ;

Ito, Y .

ORGANOMETALLICS, 1998, 17 (24) :5233-5235

[47] Nickel-catalyzed gradient copolymerizations of thiophene [J].

Locke, Jonas R. ;

McNeil, Anne J. .

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2011, 242

[48] Nickel-catalyzed carbonylative synthesis of dihydrobenzofurans [J].

Geng, Hui-Qing ;

Wang, Wei ;

Wu, Xiao-Feng .

CATALYSIS COMMUNICATIONS, 2021, 148

[49] NICKEL-CATALYZED OLEFIN INSERTION REACTIONS [J].

CHIUSOLI, GP ;

COMETTI, G .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1972, (18) :1015-&

[50] NICKEL-CATALYZED DEHYDROGENATION OF AMINES TO NITRILES [J].

YAMAZAKI, S ;

YAMAZAKI, Y .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1990, 63 (01) :301-303

← 1 2 3 4 5 →