Thermal behavior of LaPO4•nH2O and NdPO4•nH2O nanopowders

被引：14
|
作者：
Gavrichev, Konstantin S. [1 ]
Ryumin, Mikhail A. [1 ]
Tyurin, Alexander V. [1 ]
Khoroshilov, Andrey V. [1 ]
Mezentseva, Larisa P. [2 ]
Osipov, Alexander V. [2 ]
Ugolkov, Valeriy L. [2 ]
Gusarov, Viktor V. [2 ]
机构：
[1] Kurnakov Inst Gen & Inorgan Chem, Moscow, Russia
[2] RAS, Inst Silicate Chem, St Petersburg, Russia
来源：
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2010年 / 102卷 / 02期
关键词：
Thermal behavior; Nanopowders; Lanthanide orthophosphates; TRANSFORMATIONS; CRYSTALLIZATION; NANOCRYSTALS; BOEHMITE; SYSTEM; OXIDES;
D O I：
10.1007/s10973-010-0866-x
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Thermal behavior of LaPO(4)center dot nH(2)O and NdPO(4)center dot nH(2)O nanopowders from room temperature to 973 K was investigated by DSC, TA/DTG, ESM, and X-ray study. Mass loss due to the release of adsorbed and hydrate water was found in the range from 323 to 623 K. Phase transitions from hexagonal structure nanopowders to monoclinic one for bulk specimens were found above 873 K.
引用
收藏
页码：809 / 811
页数：3
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