The composition and environmental hazard of copper slags in the context of the Basel Convention

A recent comprehensive review of the characteristics and utilization of copper slags encourages (properly) several applications for this important pyrometallurgical byproduct. However, the review does not include possible environmental effects from these slags. The United Nations Basel Convention on the Transboundary Movement of Hazardous Wastes and Their Disposal characterizes copper compounds that exhibit specified hazard characteristics as hazardous wastes. In 1996, the Convention considered further characterization of these and other compounds and substances. The final characterization of copper slags is as non-hazardous, i.e., exempt from control. This decision was based in part (if not largely) on the data that are presented here. Literature reports were used to accumulate data describing the chemical composition and acid leaching of commercial copper slags from three countries. From these data, average values of chemical composition and their statistical confidence limits (95%) were calculated. The variability of the chemical analyses of three commercial slags produced over 19 or 20 months were statistically analyzed and shown to be small. The concentrations of toxic heavy metals in the slags are low and the frequency distributions of the values are narrow. Most of the data are normally distributed, validating the use of the statistics used and permitting predictions of likely values. The amounts of heavy metals extracted by an aggressive standard acid leach procedure are low and well below the United States. regulatory levels derived from drinking water standards. The results for total composition and leaching illustrate why the U.S. Environmental Protection Agency made a regulatory determination that such slags are not hazardous wastes. Later, in 1996, the Basel Convention Technical Working Group concurred and the Parties to the Convention adopted their recommendation. (C) 2004 Elsevier B.V. All rights reserved.