Reaction kinetics in liquid mixtures of formaldehyde and 1-butanol from 13C NMR spectroscopy

被引：10

作者：

Coto, B ^{[1
]}

Peschla, R ^{[1
]}

Kreiter, C ^{[1
]}

Maurer, G ^{[1
]}

机构：

[1] Univ Kaiserslautern, Fachbereich Maschinenbau & Verfahrenstech, Lehrstuhl Techn Thermodynam, D-67653 Kaiserslautern, Germany

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2003年 / 42卷 / 13期

关键词：

VAPOR-LIQUID; CHEMICAL-EQUILIBRIA; AQUEOUS-SOLUTIONS; DEUTERIUM-OXIDE; WATER; METHANOL;

D O I：

10.1021/ie030119r

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Chemical reaction kinetics for the formation/decomposition of oligomers of formaldehyde and 1-butanol in liquid mixtures of the binary system formaldehyde + 1-butanol as well as of the ternary system formaldehyde + water + 1-butanol were investigated by means of C-13 NMR spectroscopy at temperatures from 298 to 348 K at various pH. The NMR spectroscopic data was evaluated to determine rate constants for the formation/decomposition of such oligomers.

引用

页码：2934 / 2939

页数：6

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