The water resistance of surface-modified APP with melamine-TDI in LLDPE

被引：22

作者：

Sun, Cai-Ying ^{[1
]}

Zhang, Qing-Bo ^{[1
]}

Li, Bin ^{[1
]}

机构：

[1] N Forestry Univ, Dept Chem, Heilongjiang Key Lab Mol Design & Preparat Flame, Harbin 150040, Peoples R China

来源：

JOURNAL OF POLYMER RESEARCH | 2007年 / 14卷 / 06期

关键词：

APP; surface-modified; water leaching; compatibility;

D O I：

10.1007/s10965-007-9135-5

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Ammonium polyphosphate (APP) which was surface-modified with melamine (MA) and 2,4-toluene diisocyanate(TDI) in turn was used as flame-retardant in linear low density polyethylene (LLDPE). Its water resistance in LLDPE was respectively evaluated with its water-solubility, the limited oxygen index(LOI)changes and P content changes of the LLDPE which being immersed in water 180 h at room temperature. Its compatibility with LLDPE was observed with scanning electron microscope (SEM). As a result, the water-solubility of the surface-modified APP reduced. When the LLDPE was treated with surface-modified APP, its LOI and P content changes were less than that treated with unmodified-APP after being immersed in water. The surface-modified APP was better compatible with LLDPE than unmodified APP.

引用

页码：505 / 509

页数：5

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