A stable zerovalent palladium chain enveloped by a π-electron sheath of conjugated polyene ligands

被引：44

作者：

Tatsumi, Yasuki ^{[1
,2
]}

Murahashi, Tetsuro ^{[1
,2
]}

Okada, Mitsue ^{[1
,2
]}

Ogoshi, Sensuke ^{[1
,2
]}

Kurosawa, Hideo ^{[1
,2
]}

机构：

[1] Osaka Univ, Dept Appl Chem, Suita, Osaka 5650871, Japan

[2] Japan Sci & Technol Agcy, PRESTO, Suita, Osaka 5650871, Japan

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 04期

关键词：

D O I：

10.1039/b714530f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A surprisingly stable homoleptic Pd-4(0) chain complex of non-activated olefins was isolated and structurally characterized by X-ray crystallographic analysis, and the unique structure and bonding are compared to those of the corresponding dicationic [Pd-4](2+) chain sandwich complex.

引用

页码：477 / 479

页数：3

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