THE EFFECTS OF CALCIUM AND POTASSIUM DIHYDROGEN PHOSPHATE ON THE PROPERTIES OF MAGNESIUM OXYSULFATE CEMENTS

被引:3
|
作者
Luo, Kejia [1 ]
Wu, Chengyou [1 ,2 ]
Li, Zhen [1 ]
Liu, Panpan [1 ]
Pang, Ruiyang [1 ]
Chen, Cong [1 ]
Chen, Yuanji [1 ]
Zhang, Huifang [3 ,4 ]
机构
[1] Qinghai Univ, Sch Civil Engn, Xining 810016, Peoples R China
[2] Key Lab Bldg Energy Saving Mat & Engn Safety Qing, Xining 810016, Peoples R China
[3] Chinese Acad Sci, Qinghai Inst Salt Lakes, Key Lab Comprehens & Highly Efficient Utilizat Sa, Xining 810008, Peoples R China
[4] Key Lab Salt Lake Resources Chem Qinghai Prov, Xining 810008, Peoples R China
关键词
Magnesium oxysulfate cement; Setting time; Compressive strength; Hydration heat release; Porosity; HYDRATION; MECHANISM; PHASE; PHOSPHONATES; INTERFACE; SURFACE; ACID;
D O I
10.13168/cs.2019.0043
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Magnesium oxysulfate (MOS) cement is a newly-developed material, which shows the advantages of being protected from steel, being light weight, having low alkalinity, being fire-proof, and having a decorative value. Large-scale applications of MOS cement in civil engineering have been restricted by its low strength, which can be improved by adding the proper additives. Here, the effects of dihydrogen phosphate on the setting time, compressive strength, and water resistance of the MOS cement have been studied. The studies on the effects of dihydrogen phosphate on the hydration process of the MOS cement have been studied relative to the hydration-heat release rate. X-ray diffraction, scanning electron microscopy, and mercury intrusion porosimetry were used to examine the hydration products and the pore-size distribution of the MOS cement. The analytical results show that dihydrogen phosphate as an admixture can reduce the direct hydration of MgO into Mg(OH)(2), promote the formation of the 5.1.7 strength phase, and improve the strength and water resistance of the cement to some extent. However, dihydrogen phosphate will prolong the setting time of the cement to some extent.
引用
收藏
页码:7 / 17
页数:11
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