A Review on Polyethersulfone Membranes in Polar Organic Chemical Integrative Samplers: Preparation, Characterization and Innovation

被引：8
作者：
MacKeown, Henry [1 ]
Benedetti, Barbara [1 ]
Scapuzzi, Chiara [1 ]
Di Carro, Marina [1 ]
Magi, Emanuele [1 ]
机构：
[1] Univ Genoa, Dept Chem & Ind Chem, Via Dodecaneso 31, I-16146 Genoa, Italy
来源：
CRITICAL REVIEWS IN ANALYTICAL CHEMISTRY | 2024年 / 54卷 / 06期
关键词：
POCIS; polyethersulfone; membrane characterization; innovative membranes; water monitoring; ENDOCRINE-DISRUPTING COMPOUNDS; TANDEM MASS-SPECTROMETRY; PERSONAL CARE PRODUCTS; IN-SITU CALIBRATION; PASSIVE SAMPLERS; WASTE-WATER; RIVER WATER; LABORATORY CALIBRATION; POLYMERIC MATERIALS; MICROFILTRATION MEMBRANES;
D O I：
10.1080/10408347.2022.2131374
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
The membranes in polar organic chemical integrative samplers (POCIS) enclose the receiving sorbent and protect it from coming into direct contact with the environmental matrix. They have a crucial role in extending the kinetic regime of contaminant uptake, by slowing down their diffusion between the water phase and the receiving phase. The drive to improve passive sampling requires membranes with better design and enhanced performances. In this review, the preparation of standard polyethersulfone (PES) membranes for POCIS is presented, as well as methods to evaluate their composition, morphology, structure, and performance. Generally, only supplier-related morphological and structural data are provided, such as membrane type, thickness, surface area, and pore diameter. The issues related to the use of PES membranes in POCIS applications are exposed. Finally, alternative membranes to PES in POCIS are also discussed, although no better membrane has yet been developed. This review highlights the urge for more membrane characterization details and a better comprehension of the mechanisms which underlay their behavior and performance, to improve membrane selection and optimize passive sampler development.
引用
收藏
页码：1758 / 1774
页数：17
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