Synthesis and characterisation of the first E-unidentate [Ph2P(O)NP(E)Ph2]- metal complexes [Au{Ph2P(O)NP(E)Ph2-E}{Ph2P(O)NHPPh2}] and [Pd{Ph2P(O)NP(E)Ph2-E}2(H2NCH2CH2NH2)] (E = S or Se)

被引：48

作者：

Slawin, AMZ ^{[1
]}

Smith, MB ^{[1
]}

Woollins, JD ^{[1
]}

机构：

[1] Loughborough Univ Technol, Dept Chem, Loughborough LE11 3TU, Leics, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1998年 / 10期

关键词：

D O I：

10.1039/a801856a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Chloride metathesis of[AuCl(HL)] [HL = Ph2P(O)NHPPh2] or [PdCl2(en)] (en = ethane-1,2-diamine) in CH3OH with either 1 (or 2) equivalents of [Ph2P(O)NP(E)Ph-2](-) (E = S or Se) gave the neutral compounds [Au{Ph2P(O)NP(E)Ph-2-E}(HL)] or [Pd{Ph2P(O)NP(E)Ph-2-E}(2)(en)] respectively; the anionic ligands in these complexes adopt a new bonding mode and furthermore are involved in intramolecular N-H ... OP hydrogen bonding with HL or en.

引用

页码：1537 / 1539

页数：3

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