Hydrogen-bonded assembly of water and chloride in a 3D supramolecular host

被引：73
|
作者：
Ghosh, AK
Ghoshal, D
Ribas, J
Mostafa, G
Chaudhuri, NR [1 ]
机构：
[1] Jadavpur Univ, Dept Phys, Jadavpur 700032, Kolkata, India
[2] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Kolkata 700032, India
[3] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain
来源：
CRYSTAL GROWTH & DESIGN | 2006年 / 6卷 / 01期
关键词：
D O I：
10.1021/cg050423i
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The hydrogen-bonded water-chloride assembly {[(H2O)(14)Cl-2](2-)}(n), which is stabilized in a template of metal organic supramolecular host (MOSH) {[Cu(phen)(4)(adi)(OH)(2)Cl-2](2+)}(n)(adi = adipate dianion; phen = 1,10-phenanthroline), was isolated. DFT calculations corroborate the X-ray crystal structure of the hydrogen-bonded water-chloride assembly. The variable temperature magnetic study also corroborates the single-crystal structure.
引用
收藏
页码：36 / 39
页数：4
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