Ruthenium and Rhodium-Catalyzed Carbonylation Reactions

被引：178

作者：

Wu, Xiao-Feng ^{[1
]}

Neumann, Helfried ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany

来源：

CHEMCATCHEM | 2012年 / 4卷 / 04期

关键词：

carbon monoxide; carbonylation; homogeneous catalyst; rhodium; ruthenium; C-H BOND; PAUSON-KHAND REACTION; CHELATION-ASSISTED TRANSFORMATION; ONE-POT SYNTHESIS; P-TOLUIC ACID; CARBON-MONOXIDE; SELECTIVE SYNTHESIS; ARYLBORONIC ACIDS; ALPHA; BETA-UNSATURATED IMINES; OXIDATIVE CARBONYLATION;

D O I：

10.1002/cctc.201200069

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Over the last few decades, carbonylation reactions have been accepted as important chemical transformations for both academic and industrial research. Carboxylic acid derivatives are the main product of carbonylation and are widely used in organic synthesis and fine chemicals preparation. Carbonylation reactions can increase the carbon chain of parent molecules, while introducing a carbonyl group. Herein, the main developments on ruthenium- and rhodium-catalyzed carbonylation are summarized. Compared with palladium catalysts, ruthenium and rhodium catalyzed reactions are a powerful method for activating C?H bonds under mild and phosphine free conditions.

引用

页码：447 / 458

页数：12

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