Palladium-catalysed cross-coupling of organosilicon reagents

被引：370

作者：

Sore, Hannah F. ^{[1
]}

Galloway, Warren R. J. D. ^{[1
]}

Spring, David R. ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

CHEMICAL SOCIETY REVIEWS | 2012年 / 41卷 / 05期

关键词：

HIGHLY STEREOSELECTIVE-SYNTHESIS; CARBON BOND FORMATION; ONE-POT SYNTHESIS; TRIETHYLAMMONIUM BIS(CATECHOL) SILICATES; DIVERSITY-ORIENTED SYNTHESIS; TRANSITION-METAL CATALYSIS; FREE HIYAMA REACTION; ARYL BROMIDES; ORGANIC HALIDES; SODIUM-HYDROXIDE;

D O I：

10.1039/c1cs15181a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The palladium catalysed cross-coupling of organosilicon reagents with organo halides and pseudo-halides has developed over the past 30 years into an efficient and attractive carbon-carbon bond forming strategy. Extensive research within this field to expand and diversify on the scope of the organosilicon coupling reaction will continue to promote its use in the synthesis of biologically and pharmaceutically important organic molecules. The recent advances made within this area are explored in this critical review (199 references).

引用

页码：1845 / 1866

页数：22

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