Self-doped polyaniline on functionalized carbon cloth as electroactive materials for supercapacitor

被引:112
作者
Bian, Li-Jun [1 ]
Luan, Feng [1 ]
Liu, Sha-Sha [1 ]
Liu, Xiao-Xia [1 ]
机构
[1] Northeastern Univ, Dept Chem, Shenyang 110004, Peoples R China
基金
中国国家自然科学基金;
关键词
Functionalized carbon cloth; Self-doped polyaniline; Supercapacitor; ELECTROCHEMICAL ACTIVITY; CONDUCTING-POLYMER; AQUEOUS-SOLUTIONS; SURFACE; PERFORMANCE; MORPHOLOGY; OXIDATION; ACID); PH;
D O I
10.1016/j.electacta.2011.12.012
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Carbon cloth was functionalized through cyclic voltammetric scans in 2 M H2SO4 to afford functionalized carbon cloth (FC). The FC was characterized by Fourier transform infrared (FTIR) and X-ray photoelectron spectroscopy (XPS). Self-doped polyaniline (SPAN) was deposited on FC through electro-co-polymerization of aniline and metanilic acid to get SPAN/FC which showed a specific capacitance of 408 F g(-1) in 0.5 M Na2SO4, based on a constant charge-discharge experiment at a current density of 1 A g(-1). A symmetric model capacitor. SPAN/FC-SPAN/FC was assembled by using SPAN/FC as both of the electrodes and 0.5 M Na2SO4 as the electrolyte. The charge storage property and charge-discharge cycling stability of SPAN/FC-SPAN/FC were investigated by galvanostatic experiment. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:17 / 22
页数:6
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