How the type of interface can alter the behavior of an aprotic ionic liquid-water mixture entrapped in different reverse micelles: An exploratory study using an enzymatic reaction as a sensor

被引：1

作者：

Blach, Diana ^{[1
,2
]}

Girardi, Valeria R. ^{[3
]}

Silber, Juana J. ^{[3
,4
]}

Correa, N. Mariano ^{[3
,4
]}

Falcone, R. Dario ^{[3
,4
]}

机构：

[1] Univ Quindio, Fac Ciencias Agroind, Carrera 15 12 N, Armenia, Quindio, Colombia

[2] Serv Nacl Aprendizaje SENA, Ctr Agroind, Lab Nanotecnol, Cra 6 42 Norte-02, Armenia, Quindio, Colombia

[3] Univ Nacl Rio Cuarto, Dept Quim, Agencia Postal 3,CP X5804BYA,Ruta Nacl 36,Km 601, Cordoba, Argentina

[4] Univ Nacl Rio Cuarto, Inst Desarrollo Agroind & Salud IDAS, Agencia Postal 3,CP X5804BYA,Ruta Nacl 36,Km 601, Cordoba, Argentina

来源：

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS | 2022年 / 652卷

关键词：

Ionic liquids; Reverse micelles; Alkaline phosphatase; AOT; BHDC; C(4)C(1)im][TfO; ALKALINE-PHOSPHATASE; CATALYZED REACTIONS; 2-NAPHTHYL ACETATE; ALPHA-CHYMOTRYPSIN; POLAR-SOLVENTS; HYDROLYSIS; DENATURATION; CONFINEMENT; PARAMETERS; STABILITY;

D O I：

10.1016/j.colsurfa.2022.129812

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Menten parameters. In homogeneous media, the catalytic efficiency of the hydrolysis reaction is strongly dependent on the amount of water in the mixtures evaluated. In RMs the catalytic efficiency is dependent on both, the polar content and the type of surfactant used. Thus, by using a model reaction with an enzyme entrapped inside different RMs it was possible to learn that an aprotic IL:water mixture can be strongly disturbed when it is confined in a cationic or anionic RMs. This particular behavior can produce a deep impact on the technological applications of these organized systems.

引用

页数：8