Hydrogen-bond-directed self-assembly of a novel 2D → 3D polythreading with finite components based on rigid ligand

被引：13

作者：

Qiao, Lu-Yang ^{[1
,2
]}

Zhang, Jian ^{[1
]}

Li, Zhao-Ji ^{[1
]}

Qin, Ye-Yan ^{[1
]}

Yin, Pei-Xiu ^{[1
]}

Cheng, Jian-Kai ^{[1
]}

Yao, Yuan-Gen ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2011年 / 994卷 / 1-3期

关键词：

Copper; Hydrogen bonding; Polythreading; 4-Amino-1,2,4-triazole; 1,3,5-Benzenetricarboxylic acid; COORDINATION POLYMERS; CRYSTAL-STRUCTURE; NETWORK; POLYCATENATION; STRATEGIES; INTERPENETRATION; POLYROTAXANE; FRAMEWORKS; DESIGN;

D O I：

10.1016/j.molstruc.2011.02.034

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reactions of Cu(II) sulfate with 4-Amino-1,2,4-triazole (Atrz) and 1,3,5-Benzenetricarboxylic acid (H3BTC) gave a novel interesting coordination polymer {[Cu-5(BTC)(4)(HAtrz)(2)(H2O)(9)]}(n). The structure contains 2D undulated molecular layers. The BTC side arms can thread through the voids of adjacent polymeric units guided by strong intermolecular hydrogen bonding interactions, exhibiting an unusual 2D -> 3D polythreading with finite components. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：1 / 5

页数：5

共 43 条

[1] Probing the Lewis acidity and catalytic activity of the metal-organic framework [Cu3(btc)2] (BTC = benzene-1,3,5-tricarboxylate) [J].