Mixed Valency as a Strategy for Achieving Charge Delocalization in Semiconducting and Conducting Framework Materials

被引：94
作者：
Murase, Ryuichi [1 ]
Leong, Chanel F. [1 ]
D'Alessandro, Deanna M. [1 ]
机构：
[1] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia
来源：
INORGANIC CHEMISTRY | 2017年 / 56卷 / 23期
基金：
澳大利亚研究理事会;
关键词：
METAL-ORGANIC FRAMEWORKS; TUNABLE ELECTRICAL-CONDUCTIVITY; CARRIER TRANSPORT-PROPERTIES; PRUSSIAN-BLUE; COORDINATION POLYMER; CRYSTAL-STRUCTURE; ELECTRONIC-PROPERTIES; RADICAL SALTS; TRANSFER IVCT; THIN-FILMS;
D O I：
10.1021/acs.inorgchem.7b02090
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The fundamentally important phenomenon of mixed valency has been discussed in detail over the past 50 years, predominantly in the context of dinuclear complexes, which are used as model systems for understanding electron delocalization in more complex biological and physical systems. Very recently, mixed valency has been shown to be an important mechanism for charge transfer, leading to delocalization and conductivity in two- and three-dimensional framework materials such as metal-organic frameworks and related systems including covalent organic frameworks and semicrystalline semiconducting metal-organic graphenes. This Viewpoint provides a current perspective on the field of mixed-valence frameworks, where the property is either intrinsic or generated postsynthetically via an external stimulus. Aspects of the spectroscopy and applications of these materials are also discussed, highlighting the future potential for exploiting mixed valency in extended solid-state systems.
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收藏
页码：14373 / 14382
页数：10
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