115In and 19F MAS NMR study of (NH4)3InF6 phases

被引：9

作者：

Scholz, G. ^{[1
]}

Krahl, T. ^{[2
]}

Ahrens, M. ^{[1
]}

Martineau, C. ^{[3
]}

Buzare, J. Y. ^{[3
]}

Jaeger, C. ^{[2
]}

Kemnitz, E. ^{[1
]}

机构：

[1] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany

[2] Bundesanstalt Mat Prufung & Forsch, D-12489 Berlin, Germany

[3] Univ Maine, Inst Rech Ingn Mol & Mat Fonct, Lab Phys Etat Condense, CNRS,UMR 6087,FR 2575, F-72085 Le Mans 9, France

来源：

JOURNAL OF FLUORINE CHEMISTRY | 2011年 / 132卷 / 04期

关键词：

(NH4)(3)InF6; In-115 and F-19 solid state NMR; XRD; X-RAY-DIFFRACTION; CRYSTAL-STRUCTURES; TRANSITIONS; FLUORIDE; SPECTRA; SPECTROSCOPY; ELPASOLITES; NITRATE;

D O I：

10.1016/j.jfluchem.2011.01.010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This study presents for the first time an NMR spectroscopic characterization of the room and high temperature phases of (NH4)(3)InF6 using F-19 and In-115 as probe nuclei. The reversible phase transition to the cubic phase at 353 K was followed by MAS NMR in situ. Static NMR experiments of the room temperature phase and MAS NMR experiments of the high temperature phase allowed the determination of the NMR parameters of both nuclei. Finally, the scalar In-F coupling, rarely observed in solid state NMR, is evidenced in both room and high temperature phases of (NH4)3InF6, and measured in the high temperature phase. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：244 / 249

页数：6

共 21 条

[11] Solvothermal indium fluoride chemistry: Syntheses and crystal structures of K5In3F14, β-(NH4)3InF6 and [NH4]3[C6H21N4]2[In4F21] [J].