A chiral pentadecanuclear metallamacrocycle with a sextuple twisted Mobius topology

被引：64

作者：

John, Rohith P.

Park, Mira

Moon, Dohyun

Lee, Kyungjin

Hong, Seunghee

Zou, Yang

Hong, Chang Seop

Lah, Myoung Soo ^{[1
]}

机构：

[1] Hanyang Univ, Coll Sci & Technol, Dept Chem & Appl Chem, Ansan 426791, Kyunggi Do, South Korea

[2] Korea Univ, Dept Chem, Seoul 136701, South Korea

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 46期

关键词：

D O I：

10.1021/ja075945w

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A C (3) symmetric pentadecanuclear metallamacrocycle was obtained by the self-assembly of a pentadentate bridging ligand, N -phenylpropiolyl salicylhydrazide (H3L), and a manganese ion. The combination of a narrow C alpha-C beta region near the bridging domain and a bulky phenyl end away from the bridging domain as a steric domain induced clockwise twists in the cycle. The resulting macrocycle with a sextuple twisted Mobius topology was stabilized by extensive weak intramolecular interactions.

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页码：14142 / +

页数：3

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