The statistical mechanics of the electro-acoustic effects of liquids

被引：4

作者：

Yamaguchi, T ^{[1
]}

Matsuoka, T ^{[1
]}

Koda, S ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Dep Mol Design & Engn, Chikusa Ku, Aichi 4648603, Japan

来源：

JOURNAL OF CHEMICAL PHYSICS | 2003年 / 119卷 / 08期

关键词：

D O I：

10.1063/1.1592797

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The ultrasonic vibration potential (UVP) and the electrokinetic sonic amplitude (ESA) are described in terms of equilibrium time-correlation functions using the linear response theory. The reciprocal relationship between UVP and ESA is shown based on the formulation. By introducing the generalized Langevin theory and taking the hydrodynamic limit, it is discussed how the effective volume of ions in the UVP measurement is related to their partial molar thermodynamic quantities. The effective volume is proven exactly equal to the isothermal partial molar volume in the isothermal formulation. The effect of the adiabaticity of sound wave is also investigated. (C) 2003 American Institute of Physics.

引用

页码：4437 / 4448

页数：12

共 28 条

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Balucani U., 1994, DYNAMICS LIQUID STAT

[2]

Boon J. P., 1980, MOL HYDRODYNAMICS

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