Diorganogallium complexes containing tripodal Schiff bases: synthesis and structure of [N{Me2GaO(C6H4)CH=N-CH2-CH2-}3]

被引：7

作者：

Pal, Manoj K. ^{[1
]}

Kushwah, Nisha P. ^{[1
]}

Wadawale, Amey P. ^{[1
]}

Jain, Vimal K. ^{[1
]}

机构：

[1] Bhabha Atom Res Ctr, Div Chem, Bombay 400085, Maharashtra, India

来源：

JOURNAL OF CHEMICAL RESEARCH | 2010年 / 09期

关键词：

organogallium; Schiff base; crystal structure; CRYSTAL-STRUCTURE; LANTHANIDE COMPLEXES; MOLECULAR-STRUCTURES; GALLIUM COMPLEXES; INDIUM COMPLEXES; LIGANDS; FILMS; IONS;

D O I：

10.3184/030823410X12813642330916

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of triorganogallium etherates with tripodal Schiff bases in benzene gave complexes of composition [N{R2GaO(C6H3X)CH=N-CH2-CH2-}3] (R = Me, Et; X = H, OMe) in nearly quantitative yield. The molecular structure of [N{Me2GaO(C6H4)CH=N-CH2-CH2-}3] revealed that there are two different types of molecules in the crystal lattice each containing three distorted tetrahedral gallium atoms.

引用

页码：485 / 488

页数：4

共 33 条

[1]

Araki S., 2007, COMPREHENSIVE ORGANO, V9,

[2] Group 13 compounds incorporating salen ligands [J].

Atwood, DA ;

Harvey, MJ .

CHEMICAL REVIEWS, 2001, 101 (01) :37-52

[3] Molecular precursors to gallium oxide thin films [J].

Basharat, S ;

Carmalt, CJ ;

King, SJ ;

Peters, ES ;

Tocher, DA .

DALTON TRANSACTIONS, 2004, (21) :3475-3480

[4] Aerosol assisted chemical vapor deposition of In2O3 films from Me3In and donor functionalized alcohols [J].

Basharat, Siama ;

Carmalt, Claire J. ;

Barnett, Sarah A. ;

Tocher, Derek A. ;

Davies, Hywel O. .

INORGANIC CHEMISTRY, 2007, 46 (22) :9473-9480

[5] Cyclopentadiene elimination reactions for the preparation of organoindium(III) derivatives.: Crystal and molecular structures of Me2In(acac), (Me3CCH2)2In(acac), (Me)(Me3CCH2)In(acac), and [Me2InNH(t-Bu)]2 [J].

Beachley, OT ;

MacRae, DJ ;

Churchill, MR ;

Kovalevsky, AY ;

Robirds, ES .

ORGANOMETALLICS, 2003, 22 (20) :3991-4000

[6] Conformational control of spin state in iron(II) tripodal imidazole complexes [J].

Brewer, C ;

Brewer, G ;

Patil, G ;

Sun, YQ ;

Viragh, C ;

Butcher, RJ .

INORGANICA CHIMICA ACTA, 2005, 358 (12) :3441-3448

[7] Gallium(III) and indium(III) alkoxides and aryloxides [J].

Carmalt, CJ ;

King, SJ .

COORDINATION CHEMISTRY REVIEWS, 2006, 250 (5-6) :682-709

[8] A phosphorus supported multisite coordinating tris hydrazone P(S)[N(Me)N=CH-C6H4-o-OH]3 as an efficient ligand for the assembly of trinuclear metal complexes:: Synthesis, structure, and magnetism [J].

Chandrasekhar, V ;

Azhakar, R ;

Andavan, GTS ;

Krishnan, V ;

Zacchini, S ;

Bickley, JF ;

Steiner, A ;

Butcher, RJ ;

Kögerler, P .

INORGANIC CHEMISTRY, 2003, 42 (19) :5989-5998

[9] Metal chelates as emitting materials for organic electroluminescence [J].

Chen, CH ;

Shi, JM .

COORDINATION CHEMISTRY REVIEWS, 1998, 171 :161-174

[10] Structure-based description of a step-by-step synthesis of homo- and heterodinuclear (4f, 4f′) lanthanide complexes [J].

Costes, JP ;

Dahan, F ;

Nicodème, F .

INORGANIC CHEMISTRY, 2003, 42 (20) :6556-6563

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