Diorganogallium complexes containing tripodal Schiff bases: synthesis and structure of [N{Me2GaO(C6H4)CH=N-CH2-CH2-}3]

被引：7
作者：
Pal, Manoj K. [1 ]
Kushwah, Nisha P. [1 ]
Wadawale, Amey P. [1 ]
Jain, Vimal K. [1 ]
机构：
[1] Bhabha Atom Res Ctr, Div Chem, Bombay 400085, Maharashtra, India
来源：
JOURNAL OF CHEMICAL RESEARCH | 2010年 / 09期
关键词：
organogallium; Schiff base; crystal structure; CRYSTAL-STRUCTURE; LANTHANIDE COMPLEXES; MOLECULAR-STRUCTURES; GALLIUM COMPLEXES; INDIUM COMPLEXES; LIGANDS; FILMS; IONS;
D O I：
10.3184/030823410X12813642330916
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Treatment of triorganogallium etherates with tripodal Schiff bases in benzene gave complexes of composition [N{R2GaO(C6H3X)CH=N-CH2-CH2-}3] (R = Me, Et; X = H, OMe) in nearly quantitative yield. The molecular structure of [N{Me2GaO(C6H4)CH=N-CH2-CH2-}3] revealed that there are two different types of molecules in the crystal lattice each containing three distorted tetrahedral gallium atoms.
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收藏
页码：485 / 488
页数：4
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