Synthesis and crystal structure of a zwitterionic nickel(II) complex

被引：2

作者：

Dinsmore, A ^{[1
]}

Ikhide, P ^{[1
]}

Billing, DG ^{[1
]}

Fernandes, MA ^{[1
]}

Marsicano, F ^{[1
]}

Selemela, L ^{[1
]}

机构：

[1] Univ Witwatersrand, Sch Chem, ZA-2050 Johannesburg, South Africa

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2005年 / 8卷 / 03期

基金：

新加坡国家研究基金会;

关键词：

nickel; dppe; aza-thiol ligand; zwitterion; density functional calculation;

D O I：

10.1016/j.inoche.2004.12.027

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal structure of complex 3, a Ni(II)(dppe) ligated in a square planar arrangement by a novel S, N-ligand, has been determined at 123 K. The neutral and air stable complex is of interest as it shows an apparently zwitterionic structure, one counter-anion to the Ni(II) being delocalised into the backbone of the ligand. Support for this conclusion comes from an analysis of bond lengths in the complex 3, the crystal structure of which is presented and the result of a density functional calculation performed on the complex. A discussion of the mechanism leading to the observed product is presented. (C) 2005 Published by Elsevier B.V.

引用

页码：293 / 296

页数：4

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