Fe-Catalyzed Oxidation Reactions of Olefins, Alkanes, and Alcohols: Involvement of Oxo- and Peroxo Complexes

被引：62
作者：
Schroeder, Kristin [1 ]
Junge, Kathrin [1 ]
Bitterlich, Bianca [1 ]
Beller, Matthias [1 ]
机构：
[1] Univ Rostock eV, Leibniz Inst Katalyse, D-18059 Rostock, Germany
来源：
IRON CATALYSIS: FUNDAMENTALS AND APPLICATIONS | 2011年 / 33卷
关键词：
Homogeneous catalysis; Iron; Oxidation; 2-HIS-1-CARBOXYLATE FACIAL TRIAD; NONHEME IRON CATALYSTS; WET AIR OXIDATION; C-H BONDS; HYDROGEN-PEROXIDE; ALKENE EPOXIDATION; SELECTIVE OXIDATION; CIS-DIHYDROXYLATION; AROMATIC HYDROXYLATION; ENANTIOSELECTIVE EPOXIDATION;
D O I：
10.1007/978-3-642-14670-1_3
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
In this review, recent developments of iron-catalyzed oxidations of olefins (epoxidation), alkanes, arenes, and alcohols are summarized. Special focus is given on the ligand systems and the catalytic performance of the iron complexes. In addition, the mechanistic involvement of high-valent iron-oxo species is discussed.
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页码：83 / 109
页数：27
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