Carbon nanotube sensors for gas and organic vapor detection

被引:1558
作者
Li, J [1 ]
Lu, YJ
Ye, Q
Cinke, M
Han, J
Meyyappan, M
机构
[1] NASA, Ames Res Ctr, Moffett Field, CA 94035 USA
[2] ELORET Corp, Sunnyvale, CA 94087 USA
关键词
D O I
10.1021/nl034220x
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A gas sensor, fabricated by the simple casting of single-walled carbon nanotubes (SWNTs) on an interdigitated electrode (IDE), is presented for gas and organic vapor detection at room temperature. The sensor responses are linear for concentrations of sub ppm to hundreds of ppm with detection limits of 44 ppb for NO2 and 262 ppb for nitrotoluene. The time is on the order of seconds for the detection response and minutes for the recovery. The variation of the sensitivity is less than 6% for all of the tested devices, comparable with commercial metal oxide or polymer microfilm sensors while retaining the room-temperature high sensitivity of the SWNT transistor sensors and manufacturability of the commercial sensors. The extended detection capability from gas to organic vapors is attributed to direct charge transfer on individual semiconducting SWNT conductivity with additional electron hopping effects on intertube conductivity through physically adsorbed molecules between SWNTs.
引用
收藏
页码:929 / 933
页数:5
相关论文
共 14 条
[1]   Carbon nanotubes: A thermoelectric nano-nose [J].
Adu, CKW ;
Sumanasekera, GU ;
Pradhan, BK ;
Romero, HE ;
Eklund, PC .
CHEMICAL PHYSICS LETTERS, 2001, 337 (1-3) :31-35
[2]   Molecular photodesorption from single-walled carbon nanotubes [J].
Chen, RJ ;
Franklin, NR ;
Kong, J ;
Cao, J ;
Tombler, TW ;
Zhang, YG ;
Dai, HJ .
APPLIED PHYSICS LETTERS, 2001, 79 (14) :2258-2260
[3]   Carbon-nanotube-based resonant-circuit sensor for ammonia [J].
Chopra, S ;
Pham, A ;
Gaillard, J ;
Parker, A ;
Rao, AM .
APPLIED PHYSICS LETTERS, 2002, 80 (24) :4632-4634
[4]   Pore structure of raw and purified HiPco single-walled carbon nanotubes [J].
Cinke, M ;
Li, J ;
Chen, B ;
Cassell, A ;
Delzeit, L ;
Han, J ;
Meyyappan, M .
CHEMICAL PHYSICS LETTERS, 2002, 365 (1-2) :69-74
[5]   NOMENCLATURE IN EVALUATION OF ANALYTICAL METHODS INCLUDING DETECTION AND QUANTIFICATION CAPABILITIES (IUPAC RECOMMENDATIONS 1995) [J].
CURRIE, LA .
PURE AND APPLIED CHEMISTRY, 1995, 67 (10) :1699-1723
[6]  
Gardner J. W., 1999, ELECT NOSES PRINCIPL, V233
[7]   Nanotube molecular wires as chemical sensors [J].
Kong, J ;
Franklin, NR ;
Zhou, CW ;
Chapline, MG ;
Peng, S ;
Cho, KJ ;
Dai, HJ .
SCIENCE, 2000, 287 (5453) :622-625
[8]  
MARTINS H, 1998, MULTIVARIATE CALIBRA
[9]   Effects of Electrode Configuration on Polymer Carbon-Black Composite Chemical Vapor Sensor Performance [J].
Matthews, Brian ;
Li, Jing ;
Sunshine, Stephen ;
Lerner, Lee ;
Judy, Jack W. .
IEEE SENSORS JOURNAL, 2002, 2 (03) :160-168
[10]   Gas-phase catalytic growth of single-walled carbon nanotubes from carbon monoxide [J].
Nikolaev, P ;
Bronikowski, MJ ;
Bradley, RK ;
Rohmund, F ;
Colbert, DT ;
Smith, KA ;
Smalley, RE .
CHEMICAL PHYSICS LETTERS, 1999, 313 (1-2) :91-97