Nuclear Resonance Vibrational Spectroscopy: A Modern Tool to Pinpoint Site-Specific Cooperative Processes

被引：14

作者：

Wang, Hongxin ^{[1
]}

Braun, Artur ^{[2
]}

Cramer, Stephen P. ^{[1
]}

Gee, Leland B. ^{[3
]}

Yoda, Yoshitaka ^{[4
]}

机构：

[1] SETI Inst, Mountain View, CA 94043 USA

[2] Empa, Swiss Fed Labs Mat Sci & Technol, Lab High Performance Ceram, Uberlandstr 129, CH-8600 Dubendorf, Switzerland

[3] SLAC Natl Accelerator Lab, LCLS, Menlo Pk, CA 94025 USA

[4] JASRI, SPring 8, Precis Spect Div, Sayo 6795198, Japan

来源：

CRYSTALS | 2021年 / 11卷 / 08期

关键词：

nuclear resonant vibrational spectroscopy; NRVS; Mossbauer spectroscopy; isotope-specific; site-specific; vibrational modes; phonons; partial vibrational density of state; PVDOS; inelastic scattering; high-resolution monochromator; HRM; real sample temperature; an almost zero background; X-RAY-SCATTERING; PYROCOCCUS-FURIOSUS RUBREDOXIN; DENSITY-FUNCTIONAL THEORY; SYNCHROTRON-RADIATION; HIGH-PRESSURE; NITRIC-OXIDE; ACTIVE-SITE; OF-STATES; IRON; DYNAMICS;

D O I：

10.3390/cryst11080909

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Nuclear resonant vibrational spectroscopy (NRVS) is a synchrotron radiation (SR)-based nuclear inelastic scattering spectroscopy that measures the phonons (i.e., vibrational modes) associated with the nuclear transition. It has distinct advantages over traditional vibration spectroscopy and has wide applications in physics, chemistry, bioinorganic chemistry, materials sciences, and geology, as well as many other research areas. In this article, we present a scientific and figurative description of this yet modern tool for the potential users in various research fields in the future. In addition to short discussions on its development history, principles, and other theoretical issues, the focus of this article is on the experimental aspects, such as the instruments, the practical measurement issues, the data process, and a few examples of its applications. The article concludes with introduction to non-Fe-57 NRVS and an outlook on the impact from the future upgrade of SR rings.

引用

页数：42

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