Channel Partition into Nanoscale Polyhedral Cages of a Triple-Self-Interpenetrated Metal-Organic Framework with High CO2 Uptake

被引：27
作者：
Chen, Shuang-Qiu [1 ]
Zhai, Quan-Guo [1 ]
Li, Shu-Ni [1 ]
Jiang, Yu-Cheng [1 ]
Hu, Man-Cheng [1 ]
机构：
[1] Shaanxi Normal Univ, Sch Chem & Chem Engn, Key Lab Macromol Sci Shaanxi Prov, Xian 710062, Shaanxi, Peoples R China
来源：
INORGANIC CHEMISTRY | 2015年 / 54卷 / 01期
基金：
中国国家自然科学基金;
关键词：
ADSORPTION; SORPTION; LIGAND; CATENATION; SEPARATION; CAPTURE; H-2;
D O I：
10.1021/ic502254c
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reported herein is a novel porous metal-organic framework (MOF) exhibiting unique nanoscale cages derived from the 3-fold self-interpenetration of chiral eta networks based on trifurcate {Zn-2(CO2)(3)} building blocks and 1,3,5-tris(4-carboxyphenyl)benzene ligands. The attractive self-interpenetrated structural features contribute to the highest CO2 uptake capacity and CO2 binding ability among the interpenetrated MOFs.
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收藏
页码：10 / 12
页数：3
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