Syntheses, Crystal Structures and Fluorescence Properties of Two Cobalt(II) and Manganese(II) Coordination Polymers

被引：4

作者：

Lin Xing-Ye ^{[1
]}

Yang Ming-Xing ^{[1
]}

Chen Li-Juan ^{[1
]}

Xiao Zhi-Xin ^{[1
]}

Lin Shen ^{[1
]}

机构：

[1] Fujian Normal Univ, Coll Chem & Mat Sci, Fuzhou 350007, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2020年 / 36卷 / 04期

关键词：

manganese(II) complex; cobalt(II) complex; urothermal syntheses; coordination polymer; fluorescence properties; TEMPERATURE; COMPLEXES; CLUSTERS; CONSTRUCTION; FRAMEWORKS; LIGANDS;

D O I：

10.11862/CJIC.2020.072

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new metal complexes, [Mn-3(Hidc)(3)(DMI)(2)](n) (1) (H(3)idc=4,5-imidazoledicarboxylic acid, DMI=1,3-dimethyl-2-imidazolidinone) arid [Co(tbip)(DMPU)](n), (2) (H(2)tbip=5-tert-butylisophthalic acid, DMPU=N,N-dimethylpropyleneurea), have been synthesized by urothermal method. The single crystal X-ray diffraction analysis shows that complex 1 exhibits a three-dimensional structure with square-shaped pores constructed by H(3)ide and Mn(II), and DMI molecules are filled in the pores. Complex 2 is a two-dimensional network structure constructed by H(2)tbip and Co(II) using DMPU as a template, and DMPU molecules are filled in the grids of network by coordinating with Co (II). Solid fluorescence measurement reveals that complex 1 possesses blue fluorescence property with a strong emission at 462 nm. CCDC: 1943672, 1; 1943671, 2.

引用

页码：643 / 650

页数：8

共 36 条

[1] Zeolite-like metal-organic frameworks as platforms for applications:: On metalloporphyrin-based catalysts [J].

Alkordi, Mohamed H. ;

Liu, Yunling ;

Larsen, Randy W. ;

Eubank, Jarrod F. ;

Eddaoudi, Mohamed .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (38) :12639-+

[2] A tri-layer structure consisting of novel heptacobaltate clusters and single cobalt centers bridged by 5-tert-butyl isophthalate [J].

Chen, Li-Juan ;

Su, Jiang-Bo ;

Huang, Rong-Bin ;

Lin, Shen ;

Yang, Ming-Xing ;

Huang, Hua .

DALTON TRANSACTIONS, 2011, 40 (38) :9731-9736

[3] Large-Pore Apertures in a Series of Metal-Organic Frameworks [J].

Deng, Hexiang ;

Grunder, Sergio ;

Cordova, Kyle E. ;

Valente, Cory ;

Furukawa, Hiroyasu ;

Hmadeh, Mohamad ;

Gandara, Felipe ;

Whalley, Adam C. ;

Liu, Zheng ;

Asahina, Shunsuke ;

Kazumori, Hiroyoshi ;

O'Keeffe, Michael ;

Terasaki, Osamu ;

Stoddart, J. Fraser ;

Yaghi, Omar M. .

SCIENCE, 2012, 336 (6084) :1018-1023

[4] An Amino-Functionalized Metal-Organic Framework, Based on a Rare Ba12(COO)18(NO3)2 Cluster, for Efficient C3/C2/C1 Separation and Preferential Catalytic Performance [J].

Fan, Weidong ;

Wang, Yutong ;

Zhang, Qian ;

Kirchon, Angelo ;

Xiao, Zhenyu ;

Zhang, Liangliang ;

Dai, Fangna ;

Wang, Rongming ;

Sun, Daofeng .

CHEMISTRY-A EUROPEAN JOURNAL, 2018, 24 (09) :2137-2143

[5] Three microporous metal-organic frameworks assembled from dodecanuclear {NiII6LnIII6} subunits: synthesis, structure, gas adsorption and magnetism [J].

Feng, Dan-Dan ;

Dong, Hui-Ming ;

Liu, Zheng-Yu ;

Zhao, Xiao-Jun ;

Yang, En-Cui .

DALTON TRANSACTIONS, 2018, 47 (43) :15344-15352

[6] The role of temperature in the synthesis of hybrid inorganic-organic materials:: the example of cobalt succinates [J].

Forster, PM ;

Burbank, AR ;

Livage, C ;

Férey, G ;

Cheetham, AK .

CHEMICAL COMMUNICATIONS, 2004, (04) :368-369

[7] Poly[aquamanganese(II)-μ3-1H-imidazole-4,5-dicarboxylato] [J].

Gao, S ;

Huo, LH ;

Zhao, H ;

Liu, JW .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 :M155-M157

[8] Synthesis, structural versatility, luminescent and magnetic properties of a series of coordination polymers constructed from biphenyl-2,4,4′-tricarboxylate and different N-donor ligands [J].

Gu, Jin-Zhong ;

Kirillov, Alexander M. ;

Wu, Jiang ;

Lv, Dong-Yu ;

Tang, Yu ;

Wu, Jin-Cai .

CRYSTENGCOMM, 2013, 15 (47) :10287-10303

[9] Tuning Structural Topologies of Three Photoluminescent Metal-Organic Frameworks via Isomeric Biphenyldicarboxylates [J].

Guo, Feng ;

Wang, Fei ;

Yang, Hui ;

Zhang, Xiuling ;

Zhang, Jian .

INORGANIC CHEMISTRY, 2012, 51 (18) :9677-9682

[10] Metal-organic frameworks [J].

James, SL .

CHEMICAL SOCIETY REVIEWS, 2003, 32 (05) :276-288

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