Corrosion behavior of Cu55Zr35Ti10 metallic glass in the chloride media

被引:25
作者
Cai, A. H. [1 ,2 ]
Xiong, X. [2 ]
Liu, Y. [2 ]
An, W. K. [1 ]
Zhou, G. J. [1 ]
Luo, Y. [1 ]
Li, T. L. [1 ]
机构
[1] Hunan Inst Sci & Technol, Coll Mech Engn, Yueyang 414000, Peoples R China
[2] Cent S Univ, State Key Lab Powder Met, Changsha 410083, Peoples R China
关键词
Amorphous materials; Microstructure; Corrosion test; Corrosion; CU-ZR-TI; MECHANICAL-PROPERTIES; ANODIC-DISSOLUTION; THERMAL-STABILITY; PITTING CORROSION; BULK; RESISTANCE; ALLOYS; COPPER; ELECTRODISSOLUTION;
D O I
10.1016/j.matchemphys.2012.03.094
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Cu55Zr35Ti10 (at. %) ribbon was prepared by melt spinning. Its glassy structure was confirmed by X-ray diffraction (XRD) and differential scanning calorimetry (DSC), respectively. Its corrosion behavior in HCl and NaCl solutions was investigated by electrochemical polarization and immersion measurements. The surfaces before and after corrosion were observed with scanning electron microscope (SEM). The corrosion potential and corrosion resistance of the Cu55Zr35Ti10 metallic glass both decrease with increasing chloride concentration, and are higher in NaCl than in HCl. The current density in anodic curve sharply decreases when the potential reaches up to a value and the chloride concentration is more than 0.5 M in both HCl and NaCl solutions. The different corrosion behavior in HCl and NaCl is also carefully discussed. (c) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:938 / 944
页数:7
相关论文
共 44 条
[1]   Effect of additional elements on the corrosion behavior of a Cu-Zr-Ti bulk metallic glass [J].
Asami, K ;
Qin, CL ;
Zhang, T ;
Inoue, A .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2004, 375 :235-239
[2]   ANODIC DISSOLUTION OF COPPER IN FLOWING SODIUM-CHLORIDE SOLUTIONS BETWEEN 25 DEGREES AND 175 DEGREES C [J].
BACARELLA, AL ;
GRIESS, JC .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1973, 120 (04) :459-465
[3]   X-ray diffraction phase analysis of crystalline copper corrosion products after treatment in different chloride solutions [J].
Chmielová, M ;
Seidlerová, J ;
Weiss, Z .
CORROSION SCIENCE, 2003, 45 (05) :883-889
[4]   CONVECTION AND FILM INSTABILITY - COPPER ANODES IN HYDROCHLORIC ACID [J].
COOPER, RS ;
BARTLETT, JH .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1958, 105 (03) :109-116
[5]   Pitting corrosion of zirconium-based bulk glass-matrix composites [J].
Gebert, A ;
Kuehn, U ;
Baunack, S ;
Mattern, N ;
Schultz, L .
MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2006, 415 (1-2) :242-249
[6]   Effect of surface finishing of a Zr-based bulk metallic glass on its corrosion behaviour [J].
Gebert, A. ;
Gostin, P. F. ;
Schultz, L. .
CORROSION SCIENCE, 2010, 52 (05) :1711-1720
[7]   Comparison of the corrosion of bulk amorphous steel with conventional steel [J].
Gostin, P. F. ;
Gebert, A. ;
Schultz, L. .
CORROSION SCIENCE, 2010, 52 (01) :273-281
[8]  
HASHIMOTO K, 1983, AMORPHOUS METALLIC A
[9]   Effect of chloride ion on the anodic polarization behavior of the Zr65Al7.5Ni10Cu17.5 amorphous alloy in phosphate buffered solution [J].
Hiromoto, S ;
Tsai, AP ;
Sumita, M ;
Hanawa, T .
CORROSION SCIENCE, 2000, 42 (09) :1651-1660
[10]   Corrosion-fatigue study of a Zr-based bulk-metallic glass in a physiologically relevant environment [J].
Huang, Lu ;
Wang, Gongyao ;
Qiao, Dongchun ;
Liaw, Peter K. ;
Pang, Shujie ;
Wang, Jianfeng ;
Zhang, Tao .
JOURNAL OF ALLOYS AND COMPOUNDS, 2010, 504 :S159-S162