Catalytic hydroboration by an imido-hydrido complex of Mo(IV)

被引：142

作者：

Khalimon, Andrey Y. ^{[1
]}

Farha, Philip ^{[1
]}

Kuzmina, Lyudmila G. ^{[2
]}

Nikonov, Georgii I. ^{[1
]}

机构：

[1] Brock Univ, Dept Chem, St Catharines, ON L2S 3A1, Canada

[2] Kurnakov Inst Gen & Inorgan Chem RAS, Moscow 119991, Russia

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 03期

基金：

加拿大自然科学与工程研究理事会;

关键词：

ENANTIOSELECTIVE REDUCTION; PROMOTED HYDROBORATIONS; MEDIATED HYDROBORATION; TRANSITION-METALS; ORGANIC-SYNTHESIS; ZN(II) COMPLEX; CATECHOLBORANE; TITANIUM; KETONES; ALKENES;

D O I：

10.1039/c1cc14508h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The imido-hydrido complex (ArN) Mo(H)(Cl)(PMe3)(3) catalyses a variety of hydroboration reactions, including the first example of catalytic addition of HBCat to nitriles to form the bis(borylated) amines RCH2N(BCat)(2). The latter species easily undergoes chemoselective coupling with aldehydes R'C(O)H to yield imines RCH2N=C(H) R'.

引用

页码：455 / 457

页数：3

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