Preparation and properties of polysiloxane grafting multi-walled carbon nanotubes/polycarbonate nanocomposites

被引：15
作者：
Wang, Mi [1 ]
Li, Bin [1 ]
Wang, Jing [1 ]
Bai, Peng [1 ]
机构：
[1] NE Forestry Univ, Heilongjiang Key Lab Mol Design & Preparat Flame, Coll Sci, Harbin 150040, Peoples R China
来源：
POLYMERS FOR ADVANCED TECHNOLOGIES | 2011年 / 22卷 / 12期
关键词：
carbon nanotubes; polysiloxane; polycarbonate; composites; NANOTUBE NANOCOMPOSITES; MECHANICAL-PROPERTIES; ELECTRICAL-PROPERTIES; RHEOLOGICAL BEHAVIOR; COMPOSITES; MELT; FUNCTIONALIZATION; PURIFICATION; ENHANCEMENT; DISPERSION;
D O I：
10.1002/pat.1665
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Carboxyl multi-wall carbon nanotubes (MWNTs-COOH) were grafted by diaminopropyl terminated dimethylpolysiloxane (DPD) to the modified MWNTs-COOH (MWNTs-DPD). The surface structure and thermal stability of MWNTs-DPD and MWNTs-COOH were characterized using Fourier-transform infrared spectroscopy, X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis (TGA). Then PC/MWNTs-COOH and PC/MWNTs-DPD nanocomposites were prepared by the solution method and melt extrusion method. The mechanical properties, transmission electron microscopy (TEM), TGA, limiting oxygen index (LOI), UL-94 test, and permittivity test were used to evaluate the properties of the composites. The results showed that the MWNTs-DPD was dispersed well in the PC matrix, and its tensile strength, flexual strength, flexural modulus, and flame retardancy were better than that of PC/MWNTs-COOH. MWNTs-DPD can improve the electrical properties of the nanocomposites at the low loading in PC. Copyright (C) 2010 John Wiley & Sons, Ltd.
引用
收藏
页码：1738 / 1746
页数：9
相关论文
共 40 条
[1]   Work functions and surface functional groups of multiwall carbon nanotubes [J].
Ago, H ;
Kugler, T ;
Cacialli, F ;
Salaneck, WR ;
Shaffer, MSP ;
Windle, AH ;
Friend, RH .
JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (38) :8116-8121
[2]   Rational sidewall functionalization and purification of single-walled carbon nanotubes by solution-phase ozonolysis [J].
Banerjee, S ;
Wong, SS .
JOURNAL OF PHYSICAL CHEMISTRY B, 2002, 106 (47) :12144-12151
[3]   Carbon nanotube composites for thermal management [J].
Biercuk, MJ ;
Llaguno, MC ;
Radosavljevic, M ;
Hyun, JK ;
Johnson, AT ;
Fischer, JE .
APPLIED PHYSICS LETTERS, 2002, 80 (15) :2767-2769
[4]   Single-Walled Carbon Nanotube/Poly(methyl methacrylate) Composites for Electromagnetic Interference Shielding [J].
Das, Narayan Ch. ;
Liu, Yayong ;
Yang, Kaikun ;
Peng, Weiqun ;
Maiti, Spandan ;
Wang, Howard .
POLYMER ENGINEERING AND SCIENCE, 2009, 49 (08) :1627-1634
[5]   Evaluating the orientation and dispersion of carbon nanotubes inside nanocomposites by a focused-ion-beam technique [J].
Deng, Fei ;
Ogasawara, Toshio ;
Takeda, Nobuo .
MATERIALS LETTERS, 2007, 61 (29) :5095-5097
[6]   Purification of single-wall carbon nanotubes by electrochemical oxidation [J].
Fang, HT ;
Liu, CG ;
Chang, L ;
Feng, L ;
Min, L ;
Cheng, HM .
CHEMISTRY OF MATERIALS, 2004, 16 (26) :5744-5750
[7]   Functionalisation effect on the thermo-mechanical behaviour of multi-wall carbon nanotube/epoxy-compo sites [J].
Gojny, FH ;
Schulte, K .
COMPOSITES SCIENCE AND TECHNOLOGY, 2004, 64 (15) :2303-2308
[8]   Aligned single-wall carbon nanotubes in composites by melt processing methods [J].
Haggenmueller, R ;
Gommans, HH ;
Rinzler, AG ;
Fischer, JE ;
Winey, KI .
CHEMICAL PHYSICS LETTERS, 2000, 330 (3-4) :219-225
[9]   Amino-functionalized multiple-walled carbon nanotubes-polyimide nanocomposite films fabricated by in situ polymerization [J].
Hu, Yizhe ;
Wu, Liping ;
Shen, Jianfeng ;
Ye, Mingxing .
JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 110 (02) :701-705
[10]   Morphology, Thermal, and Rheological Behavior of Nylon 11/Multi-Walled Carbon Nanotube Nanocomposites Prepared by Melt Compounding [J].
Huang, Shu ;
Wang, Min ;
Liu, Tianxi ;
Zhang, Wei-De ;
Tjiu, Wuiwui Chauhari ;
He, Chaobin ;
Lu, Xuehong .
POLYMER ENGINEERING AND SCIENCE, 2009, 49 (06) :1063-1068
1234