Corrosion Resistant Polypyrrole Coated Lead-Alloy Positive Grids for Advanced Lead-Acid Batteries

被引：19

作者：

Naresh, Vangapally ^{[1
]}

Elias, Liju ^{[1
]}

Gaffoor, S. A. ^{[2
]}

Martha, Surendra K. ^{[1
]}

机构：

[1] Indian Inst Technol Hyderabad, Dept Chem, Sangareddy 502285, Telangana, India

[2] NED Energy Ltd, Hyderabad 501401, Telangana, India

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2019年 / 166卷 / 02期

关键词：

CA-SN ALLOY; FAILURE MODES; PERFORMANCE; BEHAVIOR; TECHNOLOGY; ELECTRODE; PLATES; STATE;

D O I：

10.1149/2.0211902jes

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

We herein report a method for reducing lead-alloy positive grid corrosion in lead acid batteries by developing a polypyrrole (ppy) coating on to the surface of lead-alloy grids through potentiostatic polymerization technique. The experimental results demonstrate that the presence of ppy coating significantly enhances the corrosion resistance and inhibits the oxygen evolution rate as compare to bare grids. C-rate studies of 2 V/2.6 Ah lead-acid cells show similar to 15-20% improvement in capacity at low charge-discharge rates (C/20- C/5) and similar to 10% at high C rates (C/2 and 3C) for the cells with ppy coating grids in relation to conventional lead-acid cells. (C) 2019 The Electrochemical Society.

引用

页码：A74 / A81

页数：8

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