Synthesis and properties of conjugated bimetallic ruthenium complexes with σ,σ-bridging azobenzene chains

被引：13

作者：

Yin, J ^{[1
]}

Yu, GA ^{[1
]}

Guan, JT ^{[1
]}

Mei, FS ^{[1
]}

Liu, SH ^{[1
]}

机构：

[1] Cent China Normal Univ, Coll Chem, Minist Educ, Key Lab Pesticide & Chem Biol, Wuhan 430079, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2005年 / 690卷 / 19期

基金：

中国国家自然科学基金;

关键词：

azobenzene; bimetallic; ruthenium complex; synthesis; photoisomerization; electrochemistry;

D O I：

10.1016/j.jorganchem.2005.06.031

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A versatile synthetic route to conjugated bimetallic ruthenium complexes with sigma,sigma-bridging azobenzene chains was developed, and new ruthenium complexes with various. ligands were synthesized and characterized. These bimetallic complexes showed a remarkable absorption in the visible region (lambda(max): 452-483 nm), and undergo trans-to-cis isomerization under UV light irradiation for short time. Electrochemical study showed that the metal centers in bimetallic complexes containing the CH = CH-C6H4N = NC6H4-CH = CH bridge interact with each other. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：4265 / 4271

页数：7

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