The structural transformation from 2D layers to 3D nets by solvent-mediated cation-exchange reaction

被引：8

作者：

Fu, Junhong ^{[1
]}

Fu, Junxing ^{[1
]}

Mu, Yajuan ^{[1
]}

Liu, Yanhua ^{[1
]}

Hou, Hongwei ^{[1
]}

Fan, Yaoting ^{[1
]}

机构：

[1] Zhengzhou Univ, Dept Chem, Zhengzhou 450052, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2011年 / 14卷 / 11期

关键词：

Metal-organic coordination polymer; Solvent-mediated cation-exchange reaction; Structural transformation; COORDINATION POLYMERS; ION-EXCHANGE; SOLID-STATE; SINGLE-CRYSTAL; METAL-IONS; MOLECULES; FRAMEWORK; ANION;

D O I：

10.1016/j.inoche.2011.08.018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

When metal-organic coordination polymers [M(2)(SO(4))(TTTMB)(2)(H(2)O)(4)]center dot H(2)BTEC center dot 2H(2)O (M = Cd: 1, Zn: 2; TTTMB = 1,3,5-tris(triazol-1-ylmethyl)-2,4,6-trimethylbenzene, H(4)BTEC = 1,2,4,5-benzenetetracarboxylate acid) with two dimensional layers were suspended in Cu(NO(3))(2) aqueous solution, a metal-organic coordination polymer [Cu(2)(TTTMB)(BTEC)(mu-H(2)O)(H(2)O)(4)]center dot 6H(2)O (3) with three dimensional nets would be obtained by solvent-mediated cation-exchange reaction. The direct reaction of TTTMB and H(4)BTEC with CuSO(4) in the absence of 1 or 2 affords different crystal [Cu(3)(TTTMB)(2)(H(2)BTEC)(3)(H(2)O)(3)]center dot 3H(2)O (4). (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：1823 / 1826

页数：4

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