Synthesis, Characterization, and Energetic Properties of 6-Amino-tetrazolo[1,5-b]-1,2,4,5-tetrazine-7-N-oxide: A Nitrogen-Rich Material with High Density

被引：65
|
作者：
Wei, Hao [1 ]
Zhang, Jiaheng [1 ]
Shreeve, Jean'ne M. [1 ]
机构：
[1] Univ Idaho, Dept Chem, Moscow, ID 83844 USA
来源：
CHEMISTRY-AN ASIAN JOURNAL | 2015年 / 10卷 / 05期
关键词：
perpendicular to energetic materials; nitrogen-rich compounds; N-oxide; tetrazine; tetrazole; DERIVATIVES; PRECURSOR; OXIDES; AZIDE;
D O I：
10.1002/asia.201500086
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis and energetic properties of a novel N-oxide high-nitrogen compound, 6-amino-tetrazolo[1,5-b]-1,2,4,5-tetrazine-7-N-oxide, are described. Resulting from the N-oxide and fused rings system, this molecule exhibits high density, excellent detonation properties, and acceptable impact and friction sensitivities, which suggests potential applications as an energetic material. Compared to known high-nitrogen compounds, such as 3,6-diazido-1,2,4,5-tetrazine (DiAT), 2,4,6-tri(azido)-1,3,5-triazine (TAT), and 4,4,6,6-tetra(azido)azo-1,3,5-triazine (TAAT), a marked performance and stability increase is seen. This supports the superior qualities of this new compound and the advantage of design strategy.
引用
收藏
页码：1130 / 1132
页数：3
相关论文
共 50 条
  • [1] Quantum-chemical design of tetrazolo[1,5-b][1,2,4,5]tetrazine based nitrogen-rich energetic materials
    Deswal, Sonal
    Ghule, Vikas D.
    Kumar, Tittal Ram
    Radhakrishnan, S.
    COMPUTATIONAL AND THEORETICAL CHEMISTRY, 2015, 1054 : 55 - 62
  • [2] Nitrogen-Rich Tetrazolo[1,5-b]pyridazine: Promising Building Block for Advanced Energetic Materials
    Huang, Wei
    Tang, Yongxing
    Imler, Gregory H.
    Parrish, Damon A.
    Shreeve, Jean'ne M.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (07) : 3652 - 3657
  • [3] DFT study on energetic tetrazolo-[1,5-b]-1,2,4,5-tetrazine and 1,2,4-triazolo-[4,3-b]-1,2,4,5-tetrazine derivatives
    Wei, Tao
    Zhu, Weihua
    Zhang, Jingjing
    Xiao, Heming
    JOURNAL OF HAZARDOUS MATERIALS, 2010, 179 (1-3) : 581 - 590
  • [4] Theoretical studies of 1,2,4,5-tetrazine-based energetic nitrogen-rich compounds
    Xiaohong Li
    Rui-Zhou Zhang
    Xian-Zhou Zhang
    Structural Chemistry, 2013, 24 : 393 - 400
  • [5] Theoretical studies of 1,2,4,5-tetrazine-based energetic nitrogen-rich compounds
    Li, Xiaohong
    Zhang, Rui-Zhou
    Zhang, Xian-Zhou
    STRUCTURAL CHEMISTRY, 2013, 24 (02) : 393 - 400
  • [6] Structural, thermochemical and detonation performance of derivatives of 1,2,4,5-tetrazine and 1,4 N-oxide 1,2,4,5-tetrazine as new high-performance and nitrogen-rich energetic materials
    Akbar Gholami Roknabadi
    Mohammad Hossein Keshavarz
    Karim Esmailpour
    Mehdi Zamani
    Journal of the Iranian Chemical Society, 2017, 14 : 57 - 63
  • [7] Structural, thermochemical and detonation performance of derivatives of 1,2,4,5-tetrazine and 1,4 N-oxide 1,2,4,5-tetrazine as new high-performance and nitrogen-rich energetic materials
    Roknabadi, Akbar Gholami
    Keshavarz, Mohammad Hossein
    Esmailpour, Karim
    Zamani, Mehdi
    JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2017, 14 (01) : 57 - 63
  • [8] Computational investigation and screening of high-energy-density materials: Based on nitrogen-rich 1,2,4,5-tetrazine energetic derivatives
    Zeng, Lian
    Jiang, Yuhe
    Wu, Jinting
    Li, Hongbo
    Zhang, Jianguo
    INTERNATIONAL JOURNAL OF QUANTUM CHEMISTRY, 2021, 121 (17)
  • [9] Facile synthesis of thermally stable tetrazolo[1,5-b][1,2,4]triazine substituted energetic materials: synthesis and characterization
    Kumar, Parasar
    Ghule, Vikas D.
    Dharavath, Srinivas
    DALTON TRANSACTIONS, 2023, 52 (03) : 747 - 753
  • [10] Synthesis and characterization of 3,3′-azobis(6-amino-1,2,4,5-tetrazine) DAAT -: A new promising nitrogen-rich compound
    Kerth, J
    Löbbecke, S
    PROPELLANTS EXPLOSIVES PYROTECHNICS, 2002, 27 (03) : 111 - 118
12345