Co-crystalline hydrogen bonded solids based on the alcohol-carboxylic acid-alcohol supramolecular motif

被引：17
作者：
Alshahateet, SF
Nakano, K
Bishop, R [1 ]
Craig, DC
Harris, KDM
Scudder, ML
机构：
[1] Univ New S Wales, Sch Chem Sci, Sydney, NSW 2052, Australia
[2] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales
来源：
CRYSTENGCOMM | 2004年 / 6卷
关键词：
D O I：
10.1039/b313956e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The helical tubuland diol 4 forms 1:1 hydrogen bonded co-crystalline adducts with 2-propanol and propanoic acid in space group P2(1)/c, and with benzoic acid in C2/c. In the first of these compounds, the 2-propanol molecules contribute one hydroxy group to the intermolecular ...O-H...O-H...O-H... hydrogen bond repeat unit. The co-crystals formed with propanoic acid and benzoic acid both contain a ...O-H...O=C(R)-O-H...O-H... repeat unit with the hydrogen bonds surrounding a pseudo-threefold screw axis, and where the carboxylic acid group functions like an extended alcohol hydroxy group. Aromatic offset face-face associations also play a significant role in the crystal structure of the benzoic acid compound.
引用
收藏
页码：5 / 10
页数：6
相关论文
共 40 条
  • [21] Kariuki BM, 2000, ANGEW CHEM INT EDIT, V39, P4485, DOI 10.1002/1521-3773(20001215)39:24<4485::AID-ANIE4485>3.0.CO
  • [22] 2-T
  • [23] Crystal engineering of hydroxy group hydrogen bonding: Design and synthesis of new diol lattice inclusion hosts
    Kim, S
    Bishop, R
    Craig, DC
    Dance, IG
    Scudder, ML
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2002, 67 (10) : 3221 - 3230
  • [24] REACTIONS IN INCLUSION MOLECULAR COMPLEXES .2. - TOPOCHEMICAL SOLID-STATE PHOTOADDITION OF ACETONE TO DEOXYCHOLIC-ACID
    LAHAV, M
    LEISEROWITZ, L
    POPOVITZBIRO, R
    TANG, CP
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (08) : 2542 - 2544
  • [25] MACNICOL DD, 1984, INCLUSION COMPOUNDS, V2, P1
  • [26] STRUCTURE OF A 2 - 1 COMPLEX BETWEEN DEOXYCHOLIC-ACID AND FERROCENE
    MIKI, K
    KASAI, N
    TSUTSUMI, H
    MIYATA, M
    TAKEMOTO, K
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (08) : 545 - 546
  • [27] Miyata M., 1996, COMPREHENSIVE SUPRAM, P147
  • [28] (Deoxycholic acid)2:ferrocene:: A phase transition determined by the dynamic behavior of the included guest molecules
    Müller, M
    Edwards, AJ
    Prout, K
    Simpson, WM
    Heyes, SJ
    [J]. CHEMISTRY OF MATERIALS, 2000, 12 (05) : 1314 - 1322
  • [29] Organic nanoporous structures
    Nangia, A
    [J]. CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE, 2001, 5 (2-3) : 115 - 122
  • [30] 2-1 COMPLEX OF DEOXYCHOLIC-ACID AND ETHYL-ACETATE - DISORDER IN THE STRUCTURE AT 298-K AND 163-K
    NASSIMBENI, LR
    NIVEN, ML
    STUART, DA
    ZEMKE, KJ
    [J]. JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH, 1986, 16 (04): : 557 - 567
1234