Co-crystalline hydrogen bonded solids based on the alcohol-carboxylic acid-alcohol supramolecular motif

被引：17
作者：
Alshahateet, SF
Nakano, K
Bishop, R [1 ]
Craig, DC
Harris, KDM
Scudder, ML
机构：
[1] Univ New S Wales, Sch Chem Sci, Sydney, NSW 2052, Australia
[2] Cardiff Univ, Dept Chem, Cardiff CF10 3TB, S Glam, Wales
来源：
CRYSTENGCOMM | 2004年 / 6卷
关键词：
D O I：
10.1039/b313956e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The helical tubuland diol 4 forms 1:1 hydrogen bonded co-crystalline adducts with 2-propanol and propanoic acid in space group P2(1)/c, and with benzoic acid in C2/c. In the first of these compounds, the 2-propanol molecules contribute one hydroxy group to the intermolecular ...O-H...O-H...O-H... hydrogen bond repeat unit. The co-crystals formed with propanoic acid and benzoic acid both contain a ...O-H...O=C(R)-O-H...O-H... repeat unit with the hydrogen bonds surrounding a pseudo-threefold screw axis, and where the carboxylic acid group functions like an extended alcohol hydroxy group. Aromatic offset face-face associations also play a significant role in the crystal structure of the benzoic acid compound.
引用
收藏
页码：5 / 10
页数：6
相关论文
共 40 条
  • [1] Complexation of ethanol by a helical tubuland diol host
    Ahn, PD
    Bishop, R
    Craig, DC
    Scudder, ML
    [J]. STRUCTURAL CHEMISTRY, 1999, 10 (03) : 169 - 176
  • [2] THE DEVELOPMENT OF VERSION-3 AND VERSION-4 OF THE CAMBRIDGE STRUCTURAL DATABASE SYSTEM
    ALLEN, FH
    DAVIES, JE
    GALLOY, JJ
    JOHNSON, O
    KENNARD, O
    MACRAE, CF
    MITCHELL, EM
    MITCHELL, GF
    SMITH, JM
    WATSON, DG
    [J]. JOURNAL OF CHEMICAL INFORMATION AND COMPUTER SCIENCES, 1991, 31 (02): : 187 - 204
  • [3] Pseudopolymorphic clathrate structures formed by an alicyclic dialcohol inclusion host
    Alshahateet, SF
    Bishop, R
    Craig, DC
    Scudder, ML
    Ung, AT
    [J]. STRUCTURAL CHEMISTRY, 2001, 12 (3-4) : 251 - 257
  • [4] SIR92 - a program for automatic solution of crystal structures by direct methods
    ALTOMARE, A
    CASCARANO, G
    GIACOVAZZO, G
    GUAGLIARDI, A
    BURLA, MC
    POLIDORI, G
    CAMALLI, M
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 : 435 - 435
  • [5] BISHOP R, 1999, ZH STRUKT KHIM, V40, P822
  • [6] BISHOP R, 1996, COMPREHENSIVE SUPRAM, V6, P85
  • [7] BISHOP R, UNPUB
  • [8] MAPPING THE MOLECULAR PATHWAY DURING PHOTOADDITION OF GUEST ACETOPHENONE AND PARA-FLUOROACETOPHENONE TO HOST DEOXYCHOLIC-ACID AS STUDIED BY X-RAY-DIFFRACTION IN SYSTEMS UNDERGOING SINGLE-CRYSTAL-TO-SINGLE-CRYSTAL TRANSFORMATION
    CHANG, HC
    POPOVITZBIRO, R
    LAHAV, M
    LEISEROWITZ, L
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (13) : 3883 - 3893
  • [9] COLLET A, 1980, CHEM REV, V80, P218
  • [10] MODIFICATION OF TUBE SIZE AND SHAPE IN A HELICAL TUBULAND INCLUSION LATTICE FORMED BY A NEW FAMILY OF DIOL HOSTS - SYNTHESES AND CRYSTAL-STRUCTURES
    DANCE, IG
    BISHOP, R
    HAWKINS, SC
    LIPARI, T
    SCUDDER, ML
    CRAIG, DC
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1986, (08): : 1299 - 1307
1234