Synthesis, experimental and theoretical characterization of palladium(II) and platinum(II) saccharinate complexes with 2-(2-pyridyl)benzimidazole

被引：14

作者：

Guney, Emel ^{[1
]}

Kaya, Yunus ^{[1
]}

Yilmaz, Veysel T. ^{[1
]}

Gumus, Sedat ^{[2
]}

机构：

[1] Uludag Univ, Dept Chem, Fac Arts & Sci, TR-16059 Bursa, Turkey

[2] Ondokuz Mayis Univ, Dept Phys, Fac Arts & Sci, TR-55139 Samsun, Turkey

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2011年 / 79卷 / 05期

关键词：

Saccharinate; 2-(2-Pyridyl)benzimidazole; Palladium(II); Platinum(II); DFT; VIBRATIONAL FREQUENCIES; CRYSTAL-STRUCTURES; LIGANDS; BENZIMIDAZOLE; FLUORESCENT; CHEMISTRY; POLYMERS; ZINC(II); PT(II);

D O I：

10.1016/j.saa.2011.04.038

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

New palladium(II) and platinum(II) complexes of saccharinate (sac) with 2-(2-pyridyl)benzimidazole (pybim) have been synthesized and characterized by elemental analysis and spectroscopic techniques. From the experimental studies, these complexes were formulated as [Pd(pybim)(sac)(2)] (1), and [Pt(pybim)(sac)(2)]center dot 4H(2)O (2). The ground-state geometries of both complexes were optimized using density functional theory (DFT) methods at the B3LYP level. A bidentate pybim ligand together with two N-coordinated sac ligands form the square-planar MN4 coordination geometry around the palladium(II) and platinum(II) ions. The calculated IR and UV-vis spectral data have been correlated to the experimental results. Thermal analysis data support the molecular structures of both complexes. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：1171 / 1178

页数：8

共 36 条

[1] METAL-COMPOUNDS IN THERAPY AND DIAGNOSIS [J].

ABRAMS, MJ ;

MURRER, BA .

SCIENCE, 1993, 261 (5122) :725-730

[2] Nickel(II) and copper(II) complexes of 2-(2-pyridyl)benzimidazole: synthesis and structural characterization [J].

Altaf, Muhammad ;

Stoeckli-Evans, Helen .

TRANSITION METAL CHEMISTRY, 2009, 34 (06) :613-620

[3] Metal complexes of saccharin [J].

Baran, Enrique J. ;

Yilmaz, Veysel T. .

COORDINATION CHEMISTRY REVIEWS, 2006, 250 (15-16) :1980-1999

[4] Influence of pyridine-imidazoline ligands on the reactivity of palladium-methyl complexes with carbon monoxide [J].

Bastero, A ;

Ruiz, A ;

Claver, C ;

Milani, B ;

Zangrando, E .

ORGANOMETALLICS, 2002, 21 (26) :5820-5829

[5] Synthesis and cytotoxicity of 2-(2′-pyridyl)benzimidazole complexes of palladium(II) and platinum(II) [J].

Casas, JS ;

Castiñeiras, A ;

García-Martínez, E ;

Parajó, Y ;

Pérez-Parallé, ML ;

Sánchez-González, A ;

Sordo, J .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2005, 631 (11) :2258-2264

[6] Synthesis and X-ray structure of the dinuclear platinum(II) complex with saccharin {K[Pt(sac)3(H2O)] • H2O}2:: Studies on its antiproliferative activity in aqueous solution [J].

Cavicchioli, Mauricio ;

Massabni, Antonio Carlos ;

Castellano, Eduardo Ernesto ;

Sabeh, Lilian P. B. ;

Costa-Neto, Claudio M. .

INORGANICA CHIMICA ACTA, 2007, 360 (09) :3055-3060

[7]

Frisch E., 2003, GAUSSVIEW 3 0

[8]

Frisch M., 2004, GAUSSIAN 03 REVISION, DOI DOI 10.1016/J.MOLSTRUC.2017.03.014

[9] Searching for the Magic Bullet: Anticancer Platinum Drugs Which Can Be Accumulated or Activated in the Tumor Tissue [J].

Galanski, Markus ;

Keppler, Bernhard K. .

ANTI-CANCER AGENTS IN MEDICINAL CHEMISTRY, 2007, 7 (01) :55-73

[10]

Garattini S, 2001, EUR J CANCER, V37, pS128

← 1 2 3 4 →